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| Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas | |
| Han, LN; He, XX; Yue, CX; Hu, YF; Li, LN; Chang, LP; Wang, H; Wang, JC; Wang, JC (reprint author), Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan, Peoples R China. | |
| 2016 | |
| Source Publication | FUEL
 |
| ISSN | 0016-2361 |
| Volume | 182Pages:64-72 |
| Subtype | 期刊论文 |
| Abstract | Fe doped Pd/AC (where AC is activated carbon) sorbents (1Pd5Fe/AC) were prepared and tested for removal of elemental mercury (Hg-0) from coal-derived fuel gas at medium range temperatures (150250 degrees C). It is found that the Hg-0 removal efficiency of 1Pd5Fe/AC sorbent was much higher than that of 1Pd/AC sorbent, which has previously been shown to suffer from H2S poisoning. 1Pd5Fe/AC sorbent can maintain its Hg-0 removal efficiency above 92% for 6 h at 200 degrees C. The fresh and used sorbents were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The results indicated that the Hg-0 removal active components of the 1Pd5Fe/AC sorbent were elemental Pd and Fe2O3. The elemental Pd could react with mercury vapor to form Pd-Hg amalgam. Fe2O3 could react with H2S to produce elemental sulfur which can combine with Hg-0 to form HgS. It is worth noting that PdO existed in both 1Pd5Fe/AC and 1Pd/AC sorbents and could react with H2S to form PdS, which results in the deactivation of sorbents. But Fe2O3 on the surface of 1Pd5Fe/AC sorbent can compete with PdO to react with H2S to produce elemental sulfur, thus inhibiting the deactivation of 1Pd5Fe/AC sorbent. In addition, H-2 and CO were found to promote the Hg-0 removal efficiency. The used 1Pd5Fe/AC sorbent could successfully be regenerated and reused for Hg-0 removal. (C) 2016 Published by Elsevier Ltd. |
| Keyword | Hg-0 Removal Coal Derived Fuel Gas Fe Doped Pd/ac Sorbents |
| DOI | 10.1016/j.fue1.2016.05.046 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000379102600009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26508 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | Wang, H; Wang, JC (reprint author), Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan, Peoples R China. |
| Recommended Citation GB/T 7714 | Han, LN,He, XX,Yue, CX,et al. Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas[J]. FUEL,2016,182:64-72. |
| APA | Han, LN.,He, XX.,Yue, CX.,Hu, YF.,Li, LN.,...&Wang, JC .(2016).Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas.FUEL,182,64-72. |
| MLA | Han, LN,et al."Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas".FUEL 182(2016):64-72. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Fe doping Pd_AC sorb（953KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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