Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas
Han, LN; He, XX; Yue, CX; Hu, YF; Li, LN; Chang, LP; Wang, H; Wang, JC; Wang, JC (reprint author), Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan, Peoples R China.
2016
发表期刊FUEL
ISSN0016-2361
卷号182页码:64-72
文章类型期刊论文
摘要Fe doped Pd/AC (where AC is activated carbon) sorbents (1Pd5Fe/AC) were prepared and tested for removal of elemental mercury (Hg-0) from coal-derived fuel gas at medium range temperatures (150250 degrees C). It is found that the Hg-0 removal efficiency of 1Pd5Fe/AC sorbent was much higher than that of 1Pd/AC sorbent, which has previously been shown to suffer from H2S poisoning. 1Pd5Fe/AC sorbent can maintain its Hg-0 removal efficiency above 92% for 6 h at 200 degrees C. The fresh and used sorbents were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The results indicated that the Hg-0 removal active components of the 1Pd5Fe/AC sorbent were elemental Pd and Fe2O3. The elemental Pd could react with mercury vapor to form Pd-Hg amalgam. Fe2O3 could react with H2S to produce elemental sulfur which can combine with Hg-0 to form HgS. It is worth noting that PdO existed in both 1Pd5Fe/AC and 1Pd/AC sorbents and could react with H2S to form PdS, which results in the deactivation of sorbents. But Fe2O3 on the surface of 1Pd5Fe/AC sorbent can compete with PdO to react with H2S to produce elemental sulfur, thus inhibiting the deactivation of 1Pd5Fe/AC sorbent. In addition, H-2 and CO were found to promote the Hg-0 removal efficiency. The used 1Pd5Fe/AC sorbent could successfully be regenerated and reused for Hg-0 removal. (C) 2016 Published by Elsevier Ltd.
关键词Hg-0 Removal Coal Derived Fuel Gas Fe Doped Pd/ac Sorbents
DOI10.1016/j.fue1.2016.05.046
收录类别SCI
语种英语
WOS记录号WOS:000379102600009
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26508
专题中科院上海应用物理研究所2011-2018年
通讯作者Wang, H; Wang, JC (reprint author), Taiyuan Univ Technol, Minist Educ & Shanxi Prov, Key Lab Coal Sci & Technol, Taiyuan, Peoples R China.
推荐引用方式
GB/T 7714
Han, LN,He, XX,Yue, CX,et al. Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas[J]. FUEL,2016,182:64-72.
APA Han, LN.,He, XX.,Yue, CX.,Hu, YF.,Li, LN.,...&Wang, JC .(2016).Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas.FUEL,182,64-72.
MLA Han, LN,et al."Fe doping Pd/AC sorbent efficiently improving the Hg-0 removal from the coal-derived fuel gas".FUEL 182(2016):64-72.
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