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题名: Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends
作者: Wang, HT; Fu, Z; Dong, WY; Li, YJ; Li, JY
刊名: JOURNAL OF PHYSICAL CHEMISTRY B
出版日期: 2016
卷号: 120, 期号:34, 页码:9240-9252
DOI: 10.1021/acs.jpcb.6b06761
通讯作者: Li, YJ (reprint author), Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China.
文章类型: 期刊论文
英文摘要: Micellization of in situ formed graft copolymers during reactive blending is commonly observed. Numerous studies have been carried out to minimize the formation of micelles and enhance emulsification efficiency. Herein, we investigated the formation of interfacial Janus nanomicelles (JNMs) and their compatibilization effects on immiscible polymer blends when reactive graft copolymers (RGCs) are used as compatibilizers. Poly(styrene-co-glycidyl methacrylate)graft-poly(methyl methacrylate) RGCs were synthesized and used as compatibilizers for immiscible poly(L-lactide) (PLLA)/poly(vinylidene fluoride) (PVDF) blends. Numerous nano micelles were formed in situ during melt blending by grafting of PLLA onto the RGCs. The formation and location of JNMs depended not only on the molecular architecture of the RGCs but also on the melt processing sequence and molecular weight of the components. Interfacial JNMs can effectively improve the miscibility of polymer blends, thereby enhancing the performance of immiscible polymer blends.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000382596700050
ISSN号: 1520-6106
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/26515
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

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