Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends
Wang, HT; Fu, Z; Dong, WY; Li, YJ; Li, JY; Li, YJ (reprint author), Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China.
2016
发表期刊JOURNAL OF PHYSICAL CHEMISTRY B
ISSN1520-6106
卷号120期号:34页码:9240-9252
文章类型期刊论文
摘要Micellization of in situ formed graft copolymers during reactive blending is commonly observed. Numerous studies have been carried out to minimize the formation of micelles and enhance emulsification efficiency. Herein, we investigated the formation of interfacial Janus nanomicelles (JNMs) and their compatibilization effects on immiscible polymer blends when reactive graft copolymers (RGCs) are used as compatibilizers. Poly(styrene-co-glycidyl methacrylate)graft-poly(methyl methacrylate) RGCs were synthesized and used as compatibilizers for immiscible poly(L-lactide) (PLLA)/poly(vinylidene fluoride) (PVDF) blends. Numerous nano micelles were formed in situ during melt blending by grafting of PLLA onto the RGCs. The formation and location of JNMs depended not only on the molecular architecture of the RGCs but also on the melt processing sequence and molecular weight of the components. Interfacial JNMs can effectively improve the miscibility of polymer blends, thereby enhancing the performance of immiscible polymer blends.
DOI10.1021/acs.jpcb.6b06761
收录类别SCI
语种英语
WOS记录号WOS:000382596700050
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26515
专题中科院上海应用物理研究所2011-2018年
通讯作者Li, YJ (reprint author), Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China.
推荐引用方式
GB/T 7714
Wang, HT,Fu, Z,Dong, WY,et al. Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2016,120(34):9240-9252.
APA Wang, HT,Fu, Z,Dong, WY,Li, YJ,Li, JY,&Li, YJ .(2016).Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends.JOURNAL OF PHYSICAL CHEMISTRY B,120(34),9240-9252.
MLA Wang, HT,et al."Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends".JOURNAL OF PHYSICAL CHEMISTRY B 120.34(2016):9240-9252.
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