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| Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends | |
| Wang, HT; Fu, Z; Dong, WY; Li, YJ; Li, JY; Li, YJ (reprint author), Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China. | |
| 2016 | |
| Source Publication | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| ISSN | 1520-6106 |
| Volume | 120Issue:34Pages:9240-9252 |
| Subtype | 期刊论文 |
| Abstract | Micellization of in situ formed graft copolymers during reactive blending is commonly observed. Numerous studies have been carried out to minimize the formation of micelles and enhance emulsification efficiency. Herein, we investigated the formation of interfacial Janus nanomicelles (JNMs) and their compatibilization effects on immiscible polymer blends when reactive graft copolymers (RGCs) are used as compatibilizers. Poly(styrene-co-glycidyl methacrylate)graft-poly(methyl methacrylate) RGCs were synthesized and used as compatibilizers for immiscible poly(L-lactide) (PLLA)/poly(vinylidene fluoride) (PVDF) blends. Numerous nano micelles were formed in situ during melt blending by grafting of PLLA onto the RGCs. The formation and location of JNMs depended not only on the molecular architecture of the RGCs but also on the melt processing sequence and molecular weight of the components. Interfacial JNMs can effectively improve the miscibility of polymer blends, thereby enhancing the performance of immiscible polymer blends. |
| DOI | 10.1021/acs.jpcb.6b06761 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000382596700050 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26515 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Corresponding Author | Li, YJ (reprint author), Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, 16 Xuelin Rd, Hangzhou 310036, Zhejiang, Peoples R China. |
| Recommended Citation GB/T 7714 | Wang, HT,Fu, Z,Dong, WY,et al. Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2016,120(34):9240-9252. |
| APA | Wang, HT,Fu, Z,Dong, WY,Li, YJ,Li, JY,&Li, YJ .(2016).Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends.JOURNAL OF PHYSICAL CHEMISTRY B,120(34),9240-9252. |
| MLA | Wang, HT,et al."Formation of Interfacial Janus Nanomicelles by Reactive Blending and Their Compatibilization Effects on Immiscible Polymer Blends".JOURNAL OF PHYSICAL CHEMISTRY B 120.34(2016):9240-9252. |
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| Formation of Interfa（5844KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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