Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| From Isoindigo to Dibenzonaphthyridinedione: A Building Block for Wide-Bandgap Conjugated Polymers with High Power Conversion Efficiency | |
| Cai, MA; Bao, XC; Wang, X; Zhang, HR; Qiu, M; Yang, RQ; Yang, CM; Wan, XB; Wan, XB (reprint author), Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China.; Wan, XB (reprint author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. | |
| 2016 | |
| Source Publication | CHEMISTRY OF MATERIALS
 |
| ISSN | 0897-4756 |
| Volume | 28Issue:17Pages:6196-6206 |
| Subtype | 期刊论文 |
| Abstract | Most wide-bandgap (WBG) conjugated polymers with E-g > 2.2 eV exhibit low power conversion efficiency (PCE) due to their limited absorption window. Here we report the synthesis of a novel tetracyclic fused building block dibenzonaphthyridinedione (DBND) from isoindigo and its application as an acceptor building block for wide-bandgap copolymers with improved PCE. The Stille copolymerization of this building block with 5,5'-bis(trimethylstannyl)-2,2'-bithiophene (2T) and (E)-1,2-bis(5-(trirnethylstannyl)thiophen-2-yl)ethane (TVT) results in two WBG polymers PDBND-2T (E-g 2.32 eV) and PDBND-TVT (E-g 2.23 eV), respectively. Both polymers act as excellent donors in high-performance organic solar cells (OSCs). When blended with phenyl-C-71-butyric acid methyl ester (PC71BM), PDBND-2T based OSCs exhibit a PCE of 5.75%, which makes it the broadest bandgap OSCs with PCE over 5%. PDBDN-TVT based OSCs featured a high PCE up to 6.32%. Such efficiency is the highest reported to date for a conjugated polymer at such a broad bandgap. Moreover, without additives or annealing process, PDBND-TVT based OSCs exhibit an efficiency around 6.0% with a thick active layer (240 nm) and the performance shows little sensitivity to polymer:PC71BM weight ratios (range from 1:1.5 to 1:3), which makes PDBND-TVT a potential material for processable large-area tandem or ternary OSCs. |
| DOI | 10.1021/acs.chemmater.6b02225 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000383318500023 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26517 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | Wang, X; Yang, RQ; Wan, XB (reprint author), Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China.; Wan, XB (reprint author), Univ Chinese Acad Sci, Beijing 100049, Peoples R China. |
| Recommended Citation GB/T 7714 | Cai, MA,Bao, XC,Wang, X,et al. From Isoindigo to Dibenzonaphthyridinedione: A Building Block for Wide-Bandgap Conjugated Polymers with High Power Conversion Efficiency[J]. CHEMISTRY OF MATERIALS,2016,28(17):6196-6206. |
| APA | Cai, MA.,Bao, XC.,Wang, X.,Zhang, HR.,Qiu, M.,...&Wan, XB .(2016).From Isoindigo to Dibenzonaphthyridinedione: A Building Block for Wide-Bandgap Conjugated Polymers with High Power Conversion Efficiency.CHEMISTRY OF MATERIALS,28(17),6196-6206. |
| MLA | Cai, MA,et al."From Isoindigo to Dibenzonaphthyridinedione: A Building Block for Wide-Bandgap Conjugated Polymers with High Power Conversion Efficiency".CHEMISTRY OF MATERIALS 28.17(2016):6196-6206. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| From Isoindigo to Di（6620KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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