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High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa
Qin, F; Wu, X; Wang, Y; Fan, DW; Qin, S; Yang, K; Townsend, JP; Jacobsen, SD; Wu, X (reprint author), Peking Univ, Key Lab Orogen Belts & Crustal Evolut, MOE, Beijing 100871, Peoples R China.; Wu, X (reprint author), Peking Univ, Sch Earth & Space Sci, Beijing 100871, Peoples R China.
2016
Source PublicationPHYSICS AND CHEMISTRY OF MINERALS
ISSN0342-1791
Volume43Issue:9Pages:649-659
Subtype期刊论文
AbstractThe comparative compressibility and high-pressure stability of a natural epidote (0.79 Fe-total per formula unit, Fe-tot pfu) and clinozoisite (0.40 Fe-tot pfu) were investigated by single-crystal X-ray diffraction and Raman spectroscopy. The lattice parameters of both phases exhibit continuous compression behavior up to 30 GPa without evidence of phase transformation. Pressure-volume data for both phases were fitted to a third-order Birch-Murnaghan equation of state with V (0) = 461.1(1) (3), K (0) = 115(2) GPa, and = 3.7(2) for epidote and V (0) = 457.8(1) (3), K (0) = 142(3) GPa, and = 5.2(4) for clinozoisite. In both epidote and clinozoisite, the b-axis is the stiffest direction, and the ratios of axial compressibility are 1.19:1.00:1.15 for epidote and 1.82:1.00:1.19 for clinozoisite. Whereas the compressibility of the a-axis is nearly the same for both phases, the b- and c-axes of the epidote are about 1.5 times more compressible than in clinozoisite, consistent with epidote having a lower bulk modulus. Raman spectra collected up to 40.4 GPa also show no indication of phase transformation and were used to obtain mode Gruneisen parameters (gamma (i)) for Si-O vibrations, which were found to be 0.5-0.8, typical for hydrous silicate minerals. The average pressure coefficient of Raman frequency shifts for M-O modes in epidote, 2.61(6) cm(-1)/GPa, is larger than found for clinozoisite, 2.40(6) cm(-1)/GPa, mainly due to the different compressibility of FeO6 and AlO6 octahedra in M3 sites. Epidote and clinozoisite contain about 2 wt% H2O are thus potentially important carriers of water in subducted slabs.
KeywordEpidote Clinozoisite Synchrotron Single-crystal X-ray Diffraction Compressibility
DOI10.1007/s00269-016-0824-7
Indexed BySCI
Language英语
WOS IDWOS:000385197800004
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/26533
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorWu, X (reprint author), Peking Univ, Key Lab Orogen Belts & Crustal Evolut, MOE, Beijing 100871, Peoples R China.; Wu, X (reprint author), Peking Univ, Sch Earth & Space Sci, Beijing 100871, Peoples R China.
Recommended Citation
GB/T 7714
Qin, F,Wu, X,Wang, Y,et al. High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa[J]. PHYSICS AND CHEMISTRY OF MINERALS,2016,43(9):649-659.
APA Qin, F.,Wu, X.,Wang, Y.,Fan, DW.,Qin, S.,...&Wu, X .(2016).High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa.PHYSICS AND CHEMISTRY OF MINERALS,43(9),649-659.
MLA Qin, F,et al."High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa".PHYSICS AND CHEMISTRY OF MINERALS 43.9(2016):649-659.
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