Low-temperature Electrolysis of Aluminium from 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids with Inert Anode
Zheng, Y; Peng, CH; Zheng, YJ; Tian, DY; Zuo, Y; Zheng, Y (reprint author), Anyang Inst Technol, Coll Chem & Environm Engn, Anyang 455000, Henan, Peoples R China.
2016
发表期刊INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
ISSN1452-3981
卷号11期号:7页码:6095-6109
文章类型期刊论文
摘要To solve the inherent problems rooted in the traditional Hall-Heroult electrolytic process for aluminium production, it's necessary to develop low-temperature and low-energy technology. In this work, Lewis acidic 1-butyl-3-methylimidazolium chloroaluminte ionic liquids were chosen as electrolyte in the electrolysis of aluminium. Unlike previous research, glassy carbon was used as inert anode material in the study. On this basis, cyclic voltammetric and chronoamperometric measurements were performed to explore the micro-electrochemical reaction in ionic liquids. Scanning electron microscope graphs show that smooth, compact and well-adherent deposits could be obtained at 313.2 similar to 353.2 K, 5 similar to 15 mA/cm(2). The mass content of aluminium in all the products is higher than 99%. At the same time, systematical study on the release and adsorption of Cl-2 generated from inert anode was also carried out. According to experimental results, more than 96% efficiency has been achieved at -0.1 Mpa, 313.2 similar to 373.2 K and 5 similar to 25 mA/cm(2). It's expected that the present work may be useful for industrial application of ionic liquids in aluminium production.
关键词Aluminium Electrolysis Inert Anode Ionic Liquids
DOI10.20964/2016.07.02
收录类别SCI
语种英语
WOS记录号WOS:000384905600063
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26565
专题中科院上海应用物理研究所2011-2018年
通讯作者Zheng, Y (reprint author), Anyang Inst Technol, Coll Chem & Environm Engn, Anyang 455000, Henan, Peoples R China.
推荐引用方式
GB/T 7714
Zheng, Y,Peng, CH,Zheng, YJ,et al. Low-temperature Electrolysis of Aluminium from 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids with Inert Anode[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2016,11(7):6095-6109.
APA Zheng, Y,Peng, CH,Zheng, YJ,Tian, DY,Zuo, Y,&Zheng, Y .(2016).Low-temperature Electrolysis of Aluminium from 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids with Inert Anode.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,11(7),6095-6109.
MLA Zheng, Y,et al."Low-temperature Electrolysis of Aluminium from 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids with Inert Anode".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 11.7(2016):6095-6109.
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