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| Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution | |
| Ma, Y; Zhang, BW; Ma, HJ; Yu, M; Li, LF; Li, JY; Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. | |
| 2016 | |
| Source Publication | SCIENCE CHINA-MATERIALS
 |
| ISSN | 2095-8226 |
| Volume | 59Issue:1Pages:38-50 |
| Subtype | 期刊论文 |
| Abstract | We prepared a nanofibrous adsorbent for anionic dye removal from aqueous solution by electrospinning a modified polyethylenimine (m-PEI) and polyvinylidene fluoride (PVDF) blend. The electrospun nanofibrous adsorbent was confirmed to be a nanoscale, porous material with a positively charged surface; these characteristics are quite beneficial for anionic contaminant adsorption. Experimental adsorption of an anionic dye, methyl orange (MO), demonstrates that this adsorbent can rapidly remove MO from aqueous solution; its maximum adsorption capacity was 633.3 mg g(-1), which is much higher than that of previously reported adsorbents. After immersion in a basic solution, the adsorbent was well regenerated and showed good recyclability. The adsorption performance of the nanofibrous adsorbent is greatly influenced by the temperature, initial MO concentration, and pH of the solution. We further found that MO adsorption onto the adsorbent can be described well by the pseudo-second-order kinetic model and Langmuir isotherm model. Weber-Morris plots suggested that the adsorption of MO onto the nanofibrous mat was affected by at least film diffusion and intraparticle diffusion. This study indicates that nanofibrous PEI composite mats could be promising for treatment of wastewater containing anionic dye. |
| Keyword | Nanofibrous Adsorbent Anionic Dye Electrospinning Polyethylenimine |
| DOI | 10.1007/s40843-016-0117-y |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000383101200007 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26598 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Corresponding Author | Zhang, BW; Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China. |
| Recommended Citation GB/T 7714 | Ma, Y,Zhang, BW,Ma, HJ,et al. Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution[J]. SCIENCE CHINA-MATERIALS,2016,59(1):38-50. |
| APA | Ma, Y.,Zhang, BW.,Ma, HJ.,Yu, M.,Li, LF.,...&Li, JY .(2016).Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution.SCIENCE CHINA-MATERIALS,59(1),38-50. |
| MLA | Ma, Y,et al."Polyethylenimine nanofibrous adsorbent for highly effective removal of anionic dyes from aqueous solution".SCIENCE CHINA-MATERIALS 59.1(2016):38-50. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Polyethylenimine nan（825KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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