中国科学院上海应用物理研究所机构知识库
Advanced  
CAS OpenIR  > 中科院上海应用物理研究所2011-2017年  > 期刊论文
题名: Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds
作者: Qi, GY; Wang, K; Yang, K; Zou, B
刊名: JOURNAL OF PHYSICAL CHEMISTRY C
出版日期: 2016
卷号: 120, 期号:38, 页码:21293-21298
DOI: 10.1021/acs.jpcc.6b07278
通讯作者: Wang, K ; Zou, B (reprint author), Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China.
文章类型: 期刊论文
英文摘要: We report the high-pressure behavior of dihydrogen-bonded hydrogen storage, material hydrazine bisborane (BH3N2H4BH3, HBB) via in Situ angle-dispersive X-ray diffraction (ADXRD) and Raman spectroscopy in a diamond anvil cell up to 2.0 GPa. A reversible phase transition at 0.4 GPa was confirmed by ADXRD experiments. The Rietveld refinement showed the high-pressure phase was consistent with the crystal structure of alpha'-phase (low-temperature phase). through the analysis of structure changes, Raman spectroscopy, and the Hirshfeld surface, we studied the evolution of dihydrogen bonds under high pressure and attributed the,pressure-induced phase transition to the distortion and rotation of the NH2-NH2 group. This work will further the understanding of the characteristics of dihydrogen bonds and provide some contribution to future hydrogen storage applications of HBB.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000384626800018
ISSN号: 1932-7447
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/26605
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane_ Evolution of Dihydrogen Bonds.pdf(2123KB)期刊论文作者接受稿开放获取View Download
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Qi, GY]'s Articles
[Wang, K]'s Articles
[Yang, K]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Qi, GY]‘s Articles
[Wang, K]‘s Articles
[Yang, K]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane_ Evolution of Dihydrogen Bonds.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace