Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds
Qi, GY; Wang, K; Yang, K; Zou, B; Zou, B (reprint author), Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China.
2016
发表期刊JOURNAL OF PHYSICAL CHEMISTRY C
ISSN1932-7447
卷号120期号:38页码:21293-21298
文章类型期刊论文
摘要We report the high-pressure behavior of dihydrogen-bonded hydrogen storage, material hydrazine bisborane (BH3N2H4BH3, HBB) via in Situ angle-dispersive X-ray diffraction (ADXRD) and Raman spectroscopy in a diamond anvil cell up to 2.0 GPa. A reversible phase transition at 0.4 GPa was confirmed by ADXRD experiments. The Rietveld refinement showed the high-pressure phase was consistent with the crystal structure of alpha'-phase (low-temperature phase). through the analysis of structure changes, Raman spectroscopy, and the Hirshfeld surface, we studied the evolution of dihydrogen bonds under high pressure and attributed the,pressure-induced phase transition to the distortion and rotation of the NH2-NH2 group. This work will further the understanding of the characteristics of dihydrogen bonds and provide some contribution to future hydrogen storage applications of HBB.
DOI10.1021/acs.jpcc.6b07278
收录类别SCI
语种英语
WOS记录号WOS:000384626800018
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26605
专题中科院上海应用物理研究所2011-2018年
通讯作者Wang, K; Zou, B (reprint author), Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China.
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Qi, GY,Wang, K,Yang, K,et al. Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2016,120(38):21293-21298.
APA Qi, GY,Wang, K,Yang, K,Zou, B,&Zou, B .(2016).Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds.JOURNAL OF PHYSICAL CHEMISTRY C,120(38),21293-21298.
MLA Qi, GY,et al."Pressure-Induced Phase Transition of Hydrogen Storage Material Hydrazine Bisborane: Evolution of Dihydrogen Bonds".JOURNAL OF PHYSICAL CHEMISTRY C 120.38(2016):21293-21298.
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