Rhodamine B-based ordered mesoporous organosilicas for the selective detection and adsorption of Al(III)
Xu, LJ; Han, SH; Hu, YF; Dynes, JJ; Zhang, LJ; Han, SH (reprint author), Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China.
2016
发表期刊NEW JOURNAL OF CHEMISTRY
ISSN1144-0546
卷号40期号:8页码:6752-6761
文章类型期刊论文
摘要A novel "Off-On" solid chemosensor based on ordered mesoporous organosilica material was constructed through the co-condensation of rhodamine B organosilanes (RBSi) and tetraethoxysilane (TEOS). The resulting rhodamine B-based hybrid mesoporous organosilicas (RBMSiO2) show good recognition ability for Al3+ on the basis of the "Off-On" mechanism modulated by the Al3+-promoted ring-opening process of the spirolactam structure in the rhodamine B diethylenetriamine (RBD). The photo-stability of RBD could be significantly improved after introducing rhodamine B diethylenetriamine into the framework of RBMSiO2. Upon addition of Al3+, fluorescence emission intensity could increase by 110-fold with the color change from colorless to rose-red, and the detection limit of this hybrid chemosensor towards Al3+ can be as low as 1.3 x 10(-7) M. Accordingly, the RBMSiO2 materials have great potential application in environmental and biological fields for the detection of Al3+.
DOI10.1039/c6nj00393a
收录类别SCI
语种英语
WOS记录号WOS:000381717500033
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/26616
专题中科院上海应用物理研究所2011-2018年
通讯作者Han, SH (reprint author), Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China.
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Xu, LJ,Han, SH,Hu, YF,et al. Rhodamine B-based ordered mesoporous organosilicas for the selective detection and adsorption of Al(III)[J]. NEW JOURNAL OF CHEMISTRY,2016,40(8):6752-6761.
APA Xu, LJ,Han, SH,Hu, YF,Dynes, JJ,Zhang, LJ,&Han, SH .(2016).Rhodamine B-based ordered mesoporous organosilicas for the selective detection and adsorption of Al(III).NEW JOURNAL OF CHEMISTRY,40(8),6752-6761.
MLA Xu, LJ,et al."Rhodamine B-based ordered mesoporous organosilicas for the selective detection and adsorption of Al(III)".NEW JOURNAL OF CHEMISTRY 40.8(2016):6752-6761.
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