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Significant Improvement in Thermal and UV Resistances of UHMWPE Fabric through in Situ Formation of Polysiloxane-TiO2 Hybrid Layers
Hu, JT; Gao, QH; Xu, L; Zhang, MX; Xing, Z; Guo, XJ; Zhang, K; Wu, GZ; Wu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, 2019 Jialuo Rd, Shanghai 201800, Peoples R China.
2016
Source PublicationACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
Volume8Issue:35Pages:23311-23320
Subtype期刊论文
AbstractAnatase nanocrystalline titanium dioxide coatings were produced on ultrahigh molecular weight polyethylene (UHMWPE) fabric by radiation-induced graft polymerization of gamma-methacryloxypropyl trimethoxysilane (MAPS) and subsequent cohydrolysis of the graft chains (PMAPS) with tetrabutyl titanate, followed by boiling water treatment for 180 min. The resulting material was coded as UHMWPE-g-PMAPS/TiO2 and characterized by attenuated total reflection infrared spectrometry, differential scanning calorimetry, X-ray diffraction, thermal gravimetry, and ultraviolet absorption spectroscopy, among others. The predominant form of TiO2 in the thin film was anatase. The coating layer was composed of two sublayers: an inner part consisting of an organic inorganic hybrid layer to prevent photocatalytic degradation of the matrix by TiO2 film, and an outer part consisting of anatase nanocrystalline TiO2 capable of UV absorption. This UHMWPE-g-PMAPS/TiO2 composite exhibited much better thermal resistance than conventional UHMWPE fabric, as reflected by the higher melting point, decreased maximum degradation rate, and higher char yield at 700 degrees C. Compared with UHMWPE fabric, UHMWPE-g-PMAPS/TiO2 exhibited significantly enhanced UV absorption and excellent duration of UV illumination. Specifically, the UV absorption intensity was 2.4-fold higher than that of UHMWPE fabric; the retention of the break strength of UHMWPE-g-PMAPS/TiO2 reached 92.3% after UV irradiation. This work provides an approach for addressing the issue of self-degradation of TiO2-coated polymeric materials due to the inherent photoactivity of TiO2.
KeywordRadiation-induced Graft Polymerization Sol-gel Process Titanium Oxide Uhmwpe Fabric Uv Resistance
DOI10.1021/acsami.6b04914
Indexed BySCI
Language英语
WOS IDWOS:000382902800065
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/26621
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorWu, GZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, 2019 Jialuo Rd, Shanghai 201800, Peoples R China.
Recommended Citation
GB/T 7714
Hu, JT,Gao, QH,Xu, L,et al. Significant Improvement in Thermal and UV Resistances of UHMWPE Fabric through in Situ Formation of Polysiloxane-TiO2 Hybrid Layers[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(35):23311-23320.
APA Hu, JT.,Gao, QH.,Xu, L.,Zhang, MX.,Xing, Z.,...&Wu, GZ .(2016).Significant Improvement in Thermal and UV Resistances of UHMWPE Fabric through in Situ Formation of Polysiloxane-TiO2 Hybrid Layers.ACS APPLIED MATERIALS & INTERFACES,8(35),23311-23320.
MLA Hu, JT,et al."Significant Improvement in Thermal and UV Resistances of UHMWPE Fabric through in Situ Formation of Polysiloxane-TiO2 Hybrid Layers".ACS APPLIED MATERIALS & INTERFACES 8.35(2016):23311-23320.
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