Study on structural evolution of polytetrafluoroethylene irradiated by electron beam under stretching using SAXS/WAXS

doi:10.1016/j.eurpolymj.2016.07.010

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Study on structural evolution of polytetrafluoroethylene irradiated by electron beam under stretching using SAXS/WAXS
	Li, XY; Tian, F; Tang, ZF; Yang, CM; Li, XH; Bian, FG; Wang, J; Li, XH (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai, Peoples R China.; Tang, ZF (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Nucl Radiat & Nucl Energy Technol, Shanghai, Peoples R China.
	2016
发表期刊	EUROPEAN POLYMER JOURNAL
ISSN	0014-3057
卷号	83 页码:35-41
文章类型	期刊论文
摘要	The structural evolution of polytetrafluoroethylene (PTFE) and crosslinked PTFE (XPTFE) irradiated by electron beam was studied using synchrotron wide- and small-angle X-ray scattering (WAXS/SAXS) before and after stretching. Before stretching, the crystal size, crystallinity and long period of lamellar decreased with increasing irradiation dose. After stretching, crystals had a preferred orientation along stretching direction for PTFE and crosslinked PTFE. For FIFE, at breaking point, the microvoids formed and caused the decreasing crystallinity; the lamellae were arranged periodically along stretching direction. For XPTFE with low irradiation dose, the lamellar structure was destroyed at break. However, the lamellae were observed to align more orderly in XPTFE with high irradiation dose. High irradiation dose induced the high density of crosslinking molecules and network structure which has protected the lamellar under force load. The structure evolution provided a reasonable explanation for mechanical property. (C) 2016 Elsevier Ltd. All rights reserved.
关键词	Structural Evolution Wide- And Small-angle X-ray Scattering Strain At Break Crosslinked Ptfe
DOI	10.1016/j.eurpolymj.2016.07.010
收录类别	SCI
语种	英语
WOS记录号	WOS:000385595300004
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/26636
专题	中科院上海应用物理研究所2011-2018年
通讯作者	Li, XH (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai, Peoples R China.; Tang, ZF (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Nucl Radiat & Nucl Energy Technol, Shanghai, Peoples R China.
推荐引用方式 GB/T 7714	Li, XY,Tian, F,Tang, ZF,et al. Study on structural evolution of polytetrafluoroethylene irradiated by electron beam under stretching using SAXS/WAXS[J]. EUROPEAN POLYMER JOURNAL,2016,83:35-41.
APA	Li, XY.,Tian, F.,Tang, ZF.,Yang, CM.,Li, XH.,...&Tang, ZF .(2016).Study on structural evolution of polytetrafluoroethylene irradiated by electron beam under stretching using SAXS/WAXS.EUROPEAN POLYMER JOURNAL,83,35-41.
MLA	Li, XY,et al."Study on structural evolution of polytetrafluoroethylene irradiated by electron beam under stretching using SAXS/WAXS".EUROPEAN POLYMER JOURNAL 83(2016):35-41.

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