Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst | |
| Zhang, CF; Zhang, ZX; Wang, X; Li, MR; Lu, JM; Si, R; Wang, F; Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China. | |
| 2016 | |
| Source Publication | APPLIED CATALYSIS A-GENERAL
 |
| ISSN | 0926-860X |
| Volume | 525Pages:85-93 |
| Subtype | 期刊论文 |
| Abstract | We present an efficient approach for chemoselective synthesis of various functionalized arylamines from nitroarenes over an oxygen-implanted MoS2 catalyst (O-MoS2). The HRTEM, XRD, XPS, Raman, EXAFS and NH3-TPD characterizations show the existence of (MoOx)-O-Iv structure and abundant coordinative unsaturated (CUS) Mo sites in the 2D-layer structure of O-MoS2. In the transfer hydrogenation of nitroarenes with hydrazine hydrate, the (MoOx)-O-Iv structure works as the catalytic active center. The N2H4 selectively decomposes to the active hydrogen species in polar electronic states (H delta- and He delta+), which show high chemoselectivity toward the nitro reduction over C=C, C=C, and C N groups. The O-MoS2 catalyst can be recovered in a facile manner from the reaction mixture and recycled four times without any significant loss of activity. (C) 2016 Elsevier B.V. All rights reserved. |
| Keyword | Mos2 Moox N2h4 Transfer Hydrogenation Nitro Reduction |
| DOI | 10.1016/j.apcata.2016.07.008 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000383823200010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/26666 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Corresponding Author | Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China. |
| Recommended Citation GB/T 7714 | Zhang, CF,Zhang, ZX,Wang, X,et al. Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst[J]. APPLIED CATALYSIS A-GENERAL,2016,525:85-93. |
| APA | Zhang, CF.,Zhang, ZX.,Wang, X.,Li, MR.,Lu, JM.,...&Wang, F .(2016).Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst.APPLIED CATALYSIS A-GENERAL,525,85-93. |
| MLA | Zhang, CF,et al."Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst".APPLIED CATALYSIS A-GENERAL 525(2016):85-93. |
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| Transfer hydrogenati（2034KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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