Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst

doi:10.1016/j.apcata.2016.07.008

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst
	Zhang, CF; Zhang, ZX; Wang, X; Li, MR; Lu, JM; Si, R; Wang, F; Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China.
	2016
发表期刊	APPLIED CATALYSIS A-GENERAL
ISSN	0926-860X
卷号	525 页码:85-93
文章类型	期刊论文
摘要	We present an efficient approach for chemoselective synthesis of various functionalized arylamines from nitroarenes over an oxygen-implanted MoS2 catalyst (O-MoS2). The HRTEM, XRD, XPS, Raman, EXAFS and NH3-TPD characterizations show the existence of (MoOx)-O-Iv structure and abundant coordinative unsaturated (CUS) Mo sites in the 2D-layer structure of O-MoS2. In the transfer hydrogenation of nitroarenes with hydrazine hydrate, the (MoOx)-O-Iv structure works as the catalytic active center. The N2H4 selectively decomposes to the active hydrogen species in polar electronic states (H delta- and He delta+), which show high chemoselectivity toward the nitro reduction over C=C, C=C, and C N groups. The O-MoS2 catalyst can be recovered in a facile manner from the reaction mixture and recycled four times without any significant loss of activity. (C) 2016 Elsevier B.V. All rights reserved.
关键词	Mos2 Moox N2h4 Transfer Hydrogenation Nitro Reduction
DOI	10.1016/j.apcata.2016.07.008
收录类别	SCI
语种	英语
WOS记录号	WOS:000383823200010
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/26666
专题	中科院上海应用物理研究所2011-2018年
通讯作者	Wang, F (reprint author), Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China.
推荐引用方式 GB/T 7714	Zhang, CF,Zhang, ZX,Wang, X,et al. Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst[J]. APPLIED CATALYSIS A-GENERAL,2016,525:85-93.
APA	Zhang, CF.,Zhang, ZX.,Wang, X.,Li, MR.,Lu, JM.,...&Wang, F .(2016).Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst.APPLIED CATALYSIS A-GENERAL,525,85-93.
MLA	Zhang, CF,et al."Transfer hydrogenation of nitroarenes to arylamines catalysed by an oxygen-implanted MoS2 catalyst".APPLIED CATALYSIS A-GENERAL 525(2016):85-93.

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