CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Tuning the mechanical properties of cellulose nanofibrils reinforced polyvinyl alcohol composites via altering the cellulose polymorphs
Miao, XR; Tian, F; Lin, JY; Li, H; Li, XH; Bian, FG; Zhang, XZ; Lin, JY (reprint author), Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China.; Zhang, XZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
2016
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume6Issue:86Pages:83356-83365
Subtype期刊论文
AbstractCellulose nanofibrils (CNF) with polymorphs of cellulose I and II (i.e. CNF-I and CNF-II) are different in morphology, aspect ratio, the density of functional groups and mechanical properties, which influence the reinforcement effect for polymer composites. In this work, two kinds of CNFs were fabricated from jute fibers by the TEMPO-mediated oxidation method followed by a mechanical disintegration. Highly transparent polyvinyl alcohol (PVA)/CNF composite films containing varying contents of CNF were obtained via evaporating solution blends of PVA and CNF. The mechanical and thermal properties of the PVA/CNF composites were extensively investigated. CNF-I led to a higher Young's modulus of the as-prepared composites than CNF-II did at the same content. The high density of functional groups on the surface of CNF-II enhances the interface interaction between PVA molecular chains and CNF, which result in a better toughness of the resultant composites. Meanwhile, both of CNF-I and CNF-II can improve the thermal stability and lower the degradation rate of PVA. This work provides an insight into the design of CNF reinforced composites with desired properties by altering the polymorphs of CNF.
DOI10.1039/c6ra14517e
Indexed BySCI
Language英语
WOS IDWOS:000384155100107
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/26669
Collection中科院上海应用物理研究所2011-2018年
Corresponding AuthorLin, JY; Lin, JY (reprint author), Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China.; Zhang, XZ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai Synchrotron Radiat Facil, Shanghai 201204, Peoples R China.
Recommended Citation
GB/T 7714
Miao, XR,Tian, F,Lin, JY,et al. Tuning the mechanical properties of cellulose nanofibrils reinforced polyvinyl alcohol composites via altering the cellulose polymorphs[J]. RSC ADVANCES,2016,6(86):83356-83365.
APA Miao, XR.,Tian, F.,Lin, JY.,Li, H.,Li, XH.,...&Zhang, XZ .(2016).Tuning the mechanical properties of cellulose nanofibrils reinforced polyvinyl alcohol composites via altering the cellulose polymorphs.RSC ADVANCES,6(86),83356-83365.
MLA Miao, XR,et al."Tuning the mechanical properties of cellulose nanofibrils reinforced polyvinyl alcohol composites via altering the cellulose polymorphs".RSC ADVANCES 6.86(2016):83356-83365.
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