An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds

doi:10.1002/anie.201611761

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds
	Zheng, J; Cheng, R; Lin, JH; Yu, DH; Ma, LL; Jia, LA; Zhang, L; Wang, L; Xiao, JC; Liang, SH
	2017
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
卷号	56 期号:12 页码:3196-3200
文章类型	期刊论文
摘要	Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [F-18]trifluoromethylthiolation of alpha-bromo carbonyl compounds with broad substrate scope and compatibility.
关键词	F-18-labeling Difluorocarbene Fluorine Sulfuration Trifluoromethylthiolation
DOI	10.1002/anie.201611761
收录类别	SCI
语种	英语
WOS记录号	WOS:000397329300010
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/27255
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Zheng, J,Cheng, R,Lin, JH,et al. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(12):3196-3200.
APA	Zheng, J.,Cheng, R.,Lin, JH.,Yu, DH.,Ma, LL.,...&Liang, SH.(2017).An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(12),3196-3200.
MLA	Zheng, J,et al."An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.12(2017):3196-3200.

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An Unconventional Me（777KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	请求全文