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题名:
An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds
作者: Zheng, J; Cheng, R; Lin, JH; Yu, DH; Ma, LL; Jia, LA; Zhang, L; Wang, L; Xiao, JC; Liang, SH
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期: 2017
卷号: 56, 期号:12, 页码:3196-3200
关键词: F-18-labeling ; difluorocarbene ; fluorine ; sulfuration ; trifluoromethylthiolation
DOI: 10.1002/anie.201611761
文章类型: 期刊论文
英文摘要: Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [F-18]trifluoromethylthiolation of alpha-bromo carbonyl compounds with broad substrate scope and compatibility.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000397329300010
ISSN号: 1433-7851
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/27255
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

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Recommended Citation:
Zheng, J,Cheng, R,Lin, JH,et al. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017-01-01,56(12):3196-3200.
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文件名: An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene_ Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.pdf
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