An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds
Zheng, J; Cheng, R; Lin, JH; Yu, DH; Ma, LL; Jia, LA; Zhang, L; Wang, L; Xiao, JC; Liang, SH
2017
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
卷号56期号:12页码:3196-3200
文章类型期刊论文
摘要Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [F-18]trifluoromethylthiolation of alpha-bromo carbonyl compounds with broad substrate scope and compatibility.
关键词F-18-labeling Difluorocarbene Fluorine Sulfuration Trifluoromethylthiolation
DOI10.1002/anie.201611761
收录类别SCI
语种英语
WOS记录号WOS:000397329300010
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/27255
专题中科院上海应用物理研究所2011-2018年
推荐引用方式
GB/T 7714
Zheng, J,Cheng, R,Lin, JH,et al. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(12):3196-3200.
APA Zheng, J.,Cheng, R.,Lin, JH.,Yu, DH.,Ma, LL.,...&Liang, SH.(2017).An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(12),3196-3200.
MLA Zheng, J,et al."An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.12(2017):3196-3200.
条目包含的文件 下载所有文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
An Unconventional Me(777KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 下载
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zheng, J]的文章
[Cheng, R]的文章
[Lin, JH]的文章
百度学术
百度学术中相似的文章
[Zheng, J]的文章
[Cheng, R]的文章
[Lin, JH]的文章
必应学术
必应学术中相似的文章
[Zheng, J]的文章
[Cheng, R]的文章
[Lin, JH]的文章
相关权益政策
暂无数据
收藏/分享
文件名: An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene_ Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。