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| An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds | |
| Zheng, J; Cheng, R; Lin, JH; Yu, DH; Ma, LL; Jia, LA; Zhang, L; Wang, L; Xiao, JC; Liang, SH | |
| 2017 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Volume | 56Issue:12Pages:3196-3200 |
| Subtype | 期刊论文 |
| Abstract | Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [F-18]trifluoromethylthiolation of alpha-bromo carbonyl compounds with broad substrate scope and compatibility. |
| Keyword | F-18-labeling Difluorocarbene Fluorine Sulfuration Trifluoromethylthiolation |
| DOI | 10.1002/anie.201611761 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000397329300010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27255 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Zheng, J,Cheng, R,Lin, JH,et al. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(12):3196-3200. |
| APA | Zheng, J.,Cheng, R.,Lin, JH.,Yu, DH.,Ma, LL.,...&Liang, SH.(2017).An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(12),3196-3200. |
| MLA | Zheng, J,et al."An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.12(2017):3196-3200. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| An Unconventional Me（777KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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