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题名:
Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs
作者: Xu, WW; Zeng, XC; Gao, Y
刊名: CHEMICAL PHYSICS LETTERS
出版日期: 2017
卷号: 675, 页码:35-39
DOI: 10.1016/j.cplett.2017.03.001
文章类型: 期刊论文
英文摘要: A grand unified model (GUM) has been proposed recently to understand structure anatomy and evolution of liganded gold clusters. In this work, besides the two types of elementary blocks (triangular Au-3(2e) and tetrahedral Au-4(2e)), we introduce a secondary block, namely, the icosahedral Au-13 with 8e valence electrons, noted as Au-13(8e). Using this secondary block, structural anatomy and evolution of a special group of liganded gold nanoclusters containing icosahedral Au-13 motifs can be conveniently analyzed. In addition, a new ligand-protected cluster Au-49(PR3)(10)(SR)(15)Cl-2 is predicted to exhibit high chemical and thermal stability, suggesting likelihood of its synthesis in the laboratory. (C) 2017 Elsevier B.V. All rights reserved.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000400200800007
ISSN号: 0009-2614
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/27262
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

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Recommended Citation:
Xu, WW,Zeng, XC,Gao, Y. Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs[J]. CHEMICAL PHYSICS LETTERS,2017-01-01,675:35-39.
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