Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs
Xu, WW; Zeng, XC; Gao, Y
2017
发表期刊CHEMICAL PHYSICS LETTERS
ISSN0009-2614
卷号675页码:35-39
文章类型期刊论文
摘要A grand unified model (GUM) has been proposed recently to understand structure anatomy and evolution of liganded gold clusters. In this work, besides the two types of elementary blocks (triangular Au-3(2e) and tetrahedral Au-4(2e)), we introduce a secondary block, namely, the icosahedral Au-13 with 8e valence electrons, noted as Au-13(8e). Using this secondary block, structural anatomy and evolution of a special group of liganded gold nanoclusters containing icosahedral Au-13 motifs can be conveniently analyzed. In addition, a new ligand-protected cluster Au-49(PR3)(10)(SR)(15)Cl-2 is predicted to exhibit high chemical and thermal stability, suggesting likelihood of its synthesis in the laboratory. (C) 2017 Elsevier B.V. All rights reserved.
DOI10.1016/j.cplett.2017.03.001
收录类别SCI
语种英语
WOS记录号WOS:000400200800007
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/27262
专题中科院上海应用物理研究所2011-2018年
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Xu, WW,Zeng, XC,Gao, Y. Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs[J]. CHEMICAL PHYSICS LETTERS,2017,675:35-39.
APA Xu, WW,Zeng, XC,&Gao, Y.(2017).Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs.CHEMICAL PHYSICS LETTERS,675,35-39.
MLA Xu, WW,et al."Au-13(8e): A secondary block for describing a special group of liganded gold clusters containing icosahedral Au-13 motifs".CHEMICAL PHYSICS LETTERS 675(2017):35-39.
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