Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate | |
| Wang, R; Gao, H; Zhu, DM; Yang, TY; Zhang, XM; Li, L; Yin, GZ; Zhu, LN; Feng, ZJ; Li, XL | |
| 2017 | |
| Source Publication | CARBON
 |
| ISSN | 0008-6223 |
| Volume | 114Pages:23-30 |
| Subtype | 期刊论文 |
| Abstract | The dehydration kinetics of graphene oxide (GO) were investigated by in-situ two-dimensional grazing incident X-ray diffraction. We found that the interlayer spacing of the GO membrane gradually decreased as the annealing temperature increased and as time elapsed. Surprisingly, we observed the formation of an intermediate "water-rich" GO layers at 25 degrees C with an interlayer spacing of approximately 15.2 angstrom, which was caused by the intercalation of two additional layers of water into the interlayers of the GO membrane. Moreover, three types of water trapped in GO were clearly distinguished upon isothermal annealing at various temperatures. Below 160 degrees C, the removal of "bulk water" and "confined water" resulted in a smaller interlayer spacing and the preservation of oxygen-containing functional groups. At 160 degrees C or higher, "bound water" was removed and oxygen-containing functional groups were lost, which contributed to the reduction of GO. The dehydration behaviour and structural evolution of GO investigated here is useful for understanding and controlling the properties of GO membranes for permeation, separation and electronic applications. (C) 2016 Elsevier Ltd. All rights reserved. |
| DOI | 10.1016/j.carbon.2016.11.077 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000393249600004 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27290 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Wang, R,Gao, H,Zhu, DM,et al. Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate[J]. CARBON,2017,114:23-30. |
| APA | Wang, R.,Gao, H.,Zhu, DM.,Yang, TY.,Zhang, XM.,...&Li, XL.(2017).Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate.CARBON,114,23-30. |
| MLA | Wang, R,et al."Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate".CARBON 114(2017):23-30. |
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| Dehydration behaviou（2573KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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