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| Di-1-methyl heptyl methylphosphonate (DMHMP): A promising extractant in Th-based fuel reprocessing | |
| Li, RF; Liu, CX; Zhao, HG; He, SH; Li, Z; Li, QN; Zhang, L | |
| 2017 | |
| Source Publication | SEPARATION AND PURIFICATION TECHNOLOGY
 |
| ISSN | 1383-5866 |
| Volume | 173Pages:105-112 |
| Subtype | 期刊论文 |
| Abstract | In this paper, the physical properties of tri-iso-amyl phosphate (TiAP), tri-sec-butyl phosphate (TsBP) and di-1-methyl heptyl methyl phosphonate (DMHMP) were studied and compared with tri-n-butyl-phosphate (TBP). Furthermore, the extraction behaviors of U(VI), Th(IV), nitric acid and fission products, and the extraction capacity of Th(IV) in different extractants were also investigated. The results indicated that the physical and extraction properties of DMHMP were better than that of other extractants and it is more appropriate to be used in thorium-based fuel reprocessing. A thorium-uranium co-decontamination process using DMHMP as extractant was proposed, optimized and verified by multistage countercurrent extraction using batch simulation and centrifugal extractors. By comparison with conventional Thorex process using TBP as extractant, it is found that DMHMP is more promising in thorium-based fuel reprocessing. (C) 2016 Elsevier B.V. All rights reserved. |
| Keyword | Dmhmp Physical Property Solvent Extraction Thorium-based Fuel Reprocessing |
| DOI | 10.1016/j.seppur.2016.07.035 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000388783900015 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27296 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Li, RF,Liu, CX,Zhao, HG,et al. Di-1-methyl heptyl methylphosphonate (DMHMP): A promising extractant in Th-based fuel reprocessing[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2017,173:105-112. |
| APA | Li, RF.,Liu, CX.,Zhao, HG.,He, SH.,Li, Z.,...&Zhang, L.(2017).Di-1-methyl heptyl methylphosphonate (DMHMP): A promising extractant in Th-based fuel reprocessing.SEPARATION AND PURIFICATION TECHNOLOGY,173,105-112. |
| MLA | Li, RF,et al."Di-1-methyl heptyl methylphosphonate (DMHMP): A promising extractant in Th-based fuel reprocessing".SEPARATION AND PURIFICATION TECHNOLOGY 173(2017):105-112. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Di-1-methyl heptyl m（1773KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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