Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Enhanced electrochemical sensing arsenic(III) with excellent anti-interference using amino-functionalized graphene oxide decorated gold microelectrode: XPS and XANES evidence | |
| Yang, M; Jiang, TJ; Wang, Y; Liu, JH; Li, LN; Chen, X; Huang, XJ | |
| 2017 | |
| 发表期刊 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| ISSN | 0925-4005 |
| 卷号 | 245页码:230-237 |
| 文章类型 | 期刊论文 |
| 摘要 | To date, the electrochemical method for efficient and accurate determination of As(III) in groundwater with interference-free is still a difficultly but significantly task. Herein, a reliable, high sensitive and excellent anti-interference electrochemical sensing As(III) with amino-functionalized graphene oxide (NH2-GO) decorated gold (Au) microelectrode was developed in mild media with square wave anodic stripping voltammeter (SWASV). Taking advantage of the synergy between the strong absorption capability of NH2-GO and the excellent electrocatalytic ability of Au microwire, the NH2-GO modified Au microelectrode exhibits the enhanced electrochemical performance toward As(III). No obvious interference from other commonly coexisting ions on the determination of As(III) was observed. Furthermore, the robust stability and reproducibility of the electrodes were obtained. Under the optimized conditions, the limit of detection (3 sigma method) toward As(III) was 0.162 ppb with a sensitivity of 130.631 mu A ppb(-1) cm(-2). Notably, the possible mechanism of the enhanced stripping signal was preliminarily explored by using X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure (XANES) techniques. Finally, the analytical application of the raised means on the detection of As(III) in Xingwangzhuang Village groundwater, Inner Mongolia, has been successfully verified. (C) 2017 Elsevier B.V. All rights reserved. |
| 关键词 | Electrochemical Sensing Arsenic(Iii) Nh2-go Anti-interference Xps And Xanes |
| DOI | 10.1016/j.snb.2017.01.139 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000398760700029 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.sinap.ac.cn/handle/331007/27313 |
| 专题 | 中科院上海应用物理研究所2011-2018年 |
| 推荐引用方式 GB/T 7714 | Yang, M,Jiang, TJ,Wang, Y,et al. Enhanced electrochemical sensing arsenic(III) with excellent anti-interference using amino-functionalized graphene oxide decorated gold microelectrode: XPS and XANES evidence[J]. SENSORS AND ACTUATORS B-CHEMICAL,2017,245:230-237. |
| APA | Yang, M.,Jiang, TJ.,Wang, Y.,Liu, JH.,Li, LN.,...&Huang, XJ.(2017).Enhanced electrochemical sensing arsenic(III) with excellent anti-interference using amino-functionalized graphene oxide decorated gold microelectrode: XPS and XANES evidence.SENSORS AND ACTUATORS B-CHEMICAL,245,230-237. |
| MLA | Yang, M,et al."Enhanced electrochemical sensing arsenic(III) with excellent anti-interference using amino-functionalized graphene oxide decorated gold microelectrode: XPS and XANES evidence".SENSORS AND ACTUATORS B-CHEMICAL 245(2017):230-237. |
| 条目包含的文件 | 下载所有文件 | |||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Enhanced electrochem（2437KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论