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| Insights into the Coordination and Extraction of Yttrium(III) Ions with a Phenoxyacetic Acid Ionic-Liquid Extractant | |
| Guo, XG; Yang, RO; Gong, Y; Jiang, Z; Dong, YM; Sun, XQ | |
| 2017 | |
| 发表期刊 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| ISSN | 1434-1948 |
| 卷号 | 2017期号:17页码:2332-2339 |
| 文章类型 | 期刊论文 |
| 摘要 | Phenoxyacetic acid type extractants such as sec-octylphenoxyacetic acid (CA-12), sec-nonylphenoxyacetic acid (CA-100), and the resulting bifunctional ionic-liquid extractants were developed to separate yttrium from heavy rare-earth elements (REEs). To obtain information on the coordination chemistry of this type of bifunctional ionic-liquid extractant, the CA-12 analogue n-octylphenoxyacetic acid (HOCTPOA) was synthesized, and its structure was characterized by single-crystal X-ray diffraction analysis. Then, a bifunctional ionic-liquid extractant based on HOCTPOA, namely, [N-1888][OCTPOA] (N-1888 is methyltrioctylammonium) was synthesized. The study of the extraction of yttrium with [N-1888][OCTPOA] in chloride media was conducted by IR spectroscopy, logD versus logC slope analysis, ESI-MS, extended X-ray absorption fine structure (EXAFS), and DFT studies. The EXAFS data indicate that a Y-III extraction complex with phenoxyacetic acid formed. Three possible Y-III coordination cations were calculated by the DFT method, and the obtained Y-O bond lengths were comparable to the results from EXAFS fitting. A possible structure for the overall extracted complex was proposed, and this knowledge should contribute to a better understanding of the extraction process with phenoxyacetate-type bifunctional ionic liquids. |
| 关键词 | Rare Earths Ionic Liquids Extraction Saponification Density Functional Calculations |
| DOI | 10.1002/ejic.201601491 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000400991200005 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.sinap.ac.cn/handle/331007/27354 |
| 专题 | 中科院上海应用物理研究所2011-2018年 |
| 推荐引用方式 GB/T 7714 | Guo, XG,Yang, RO,Gong, Y,et al. Insights into the Coordination and Extraction of Yttrium(III) Ions with a Phenoxyacetic Acid Ionic-Liquid Extractant[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017,2017(17):2332-2339. |
| APA | Guo, XG,Yang, RO,Gong, Y,Jiang, Z,Dong, YM,&Sun, XQ.(2017).Insights into the Coordination and Extraction of Yttrium(III) Ions with a Phenoxyacetic Acid Ionic-Liquid Extractant.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017(17),2332-2339. |
| MLA | Guo, XG,et al."Insights into the Coordination and Extraction of Yttrium(III) Ions with a Phenoxyacetic Acid Ionic-Liquid Extractant".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2017.17(2017):2332-2339. |
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| Insights into the Co（1444KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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