Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U
Zhu, TJ; Huang, W; Zheng, HY; She, CF; Jiang, F; Wang, XB; Yu, G; Long, DW; Li, QN
2017
发表期刊JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN1588-2780
卷号3页码:485-
文章类型期刊论文
摘要Electrochemical behaviors of U4+ in LiCl-KCl-UF4 eutectic and deposition of U metal were investigated. It was found that the presence of F- has influence on the diffusion of U3+ and U4+ as comparing to data obtained in pure chloride molten salts. Electrochemical deposition of U was carried out by using pulse current electrolysis. Characterization results indicate that U metal was obtained at the cathode, implying U metal can be directly deposited from LiCl-KCl-UF4 eutectic in this case and the extractive ratio is calculated to be 98%. Our results demonstrate feasible separation of U from LiCl-KCl-UF4 molten salt by electrochemical method.
关键词F- Influence Uranium Ion Licl-kcl Molten Salt Spent Fuel
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/27358
专题中科院上海应用物理研究所2011-2018年
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Zhu, TJ,Huang, W,Zheng, HY,et al. Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017,3:485-.
APA Zhu, TJ.,Huang, W.,Zheng, HY.,She, CF.,Jiang, F.,...&Li, QN.(2017).Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,3,485-.
MLA Zhu, TJ,et al."Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 3(2017):485-.
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