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题名:
Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U
作者: Zhu, TJ; Huang, W; Zheng, HY; She, CF; Jiang, F; Wang, XB; Yu, G; Long, DW; Li, QN
刊名: JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
出版日期: 2017
卷号: 3, 页码:485-
关键词: F- influence ; Uranium ion ; LiCl-KCl molten salt ; Spent fuel
文章类型: 期刊论文
英文摘要: Electrochemical behaviors of U4+ in LiCl-KCl-UF4 eutectic and deposition of U metal were investigated. It was found that the presence of F- has influence on the diffusion of U3+ and U4+ as comparing to data obtained in pure chloride molten salts. Electrochemical deposition of U was carried out by using pulse current electrolysis. Characterization results indicate that U metal was obtained at the cathode, implying U metal can be directly deposited from LiCl-KCl-UF4 eutectic in this case and the extractive ratio is calculated to be 98%. Our results demonstrate feasible separation of U from LiCl-KCl-UF4 molten salt by electrochemical method.
收录类别: SCI
语种: 英语
ISSN号: 1588-2780
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/27358
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

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Recommended Citation:
Zhu, TJ,Huang, W,Zheng, HY,et al. Investigating the influence of F- on U4+ in molten LiCl-KCl-UF4 system and electro-deposition of U[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017-01-01,3:485-.
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