Low-temperature hydrogen production from water and methanol using Pt/alpha-MoC catalysts

doi:10.1038/nature21672

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Low-temperature hydrogen production from water and methanol using Pt/alpha-MoC catalysts
	Lin, LL; Zhou, W; Gao, R; Yao, SY; Zhang, X; Xu, WQ; Zheng, SJ; Jiang, Z; Yu, QL; Li, YW; Shi, C; Wen, XD; Ma, D
	2017
发表期刊	NATURE
ISSN	0028-0836
卷号	544 期号:7648 页码:80-+
文章类型	期刊论文
摘要	Polymer electrolyte membrane fuel cells (PEMFCs) running on hydrogen are attractive alternative power supplies for a range of applications(1-3), with in situ release of the required hydrogen from a stable liquid offering one way of ensuring its safe storage and transportation(4,5) before use. The use of methanol is particularly interesting in this regard, because it is inexpensive and can reform itself with water to release hydrogen with a high gravimetric density of 18.8 per cent by weight. But traditional reforming of methanol steam operates at relatively high temperatures (200-350 degrees Celsius)(6-8), so the focus for vehicle and portable PEMFC applications(9) has been on aqueous-phase reforming of methanol (APRM). This method requires less energy, and the simpler and more compact device design allows direct integration into PEMFC stacks(10,11). There remains, however, the need for an efficient APRM catalyst. Here we report that platinum (Pt) atomically dispersed on a-molybdenum carbide (alpha-MoC) enables low-temperature (150-190 degrees Celsius), base-free hydrogen production through APRM, with an average turnover frequency reaching 18,046 moles of hydrogen per mole of platinum per hour. We attribute this exceptional hydrogen production-which far exceeds that of previously reported low-temperature APRM catalysts-to the outstanding ability of a-MoC to induce water dissociation, and to the fact that platinum and a-MoC act in synergy to activate methanol and then to reform it.
DOI	10.1038/nature21672
收录类别	SCI
语种	英语
WOS记录号	WOS:000398323300036
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/27368
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Lin, LL,Zhou, W,Gao, R,et al. Low-temperature hydrogen production from water and methanol using Pt/alpha-MoC catalysts[J]. NATURE,2017,544(7648):80-+.
APA	Lin, LL.,Zhou, W.,Gao, R.,Yao, SY.,Zhang, X.,...&Ma, D.(2017).Low-temperature hydrogen production from water and methanol using Pt/alpha-MoC catalysts.NATURE,544(7648),80-+.
MLA	Lin, LL,et al."Low-temperature hydrogen production from water and methanol using Pt/alpha-MoC catalysts".NATURE 544.7648(2017):80-+.

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Low-temperature hydr（5321KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	请求全文