MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries
Li, MC; Yu, SC; Chen, ZH; Wang, ZY; Lv, FC; Nan, B; Zhu, YG; Shi, Y; Wang, WX; Wu, SF; Liu, HT; Tang, YG; Lu, ZG
2017
发表期刊INORGANIC CHEMISTRY FRONTIERS
ISSN2052-1553
卷号4期号:2页码:289-295
文章类型期刊论文
摘要Molybdenum carbide (MoC)/graphitic carbon nanocomposites are synthesized using a green and facile method. Well-crystallized MoC ultrafine nanoparticles (<5 nm diameter) are formed in situ inside the pores of a highly conductive graphitic carbon matrix. The resulting MoC/graphitic carbon nanocomposites exhibit very promising electrochemical performance when evaluated as anodes in LIBs and SIBs, because the synergistic effects of the small MoC nanoparticles provide fast and efficient transport and porous graphitic carbon can prevent continual rupturing as well as enhance conductivity. Meanwhile, this novel material has potential for broad application in rechargeable batteries, maintaining a reversible capacity of 742 mA h g(-1) after 50 cycles at 200 mA g(-1) for LIBs and a discharge capacity of 250 mA h g(-1) after 50 cycles at 50 mA g(-1) for SIBs. Furthermore, the required Mo can be recovered from wastewater, which gives this method an added environmental benefit and in return satisfy the current demand for sustainable development.
DOI10.1039/c6qi00465b
收录类别SCI
语种英语
WOS记录号WOS:000395802300008
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被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/27385
专题中科院上海应用物理研究所2011-2018年
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Li, MC,Yu, SC,Chen, ZH,et al. MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries[J]. INORGANIC CHEMISTRY FRONTIERS,2017,4(2):289-295.
APA Li, MC.,Yu, SC.,Chen, ZH.,Wang, ZY.,Lv, FC.,...&Lu, ZG.(2017).MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries.INORGANIC CHEMISTRY FRONTIERS,4(2),289-295.
MLA Li, MC,et al."MoC ultrafine nanoparticles confined in porous graphitic carbon as extremely stable anode materials for lithium- and sodium-ion batteries".INORGANIC CHEMISTRY FRONTIERS 4.2(2017):289-295.
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