Passivated perovskite crystallization and stability in organic-inorganic halide solar cells by doping a donor polymer

doi:10.1039/c6ta08970d

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Passivated perovskite crystallization and stability in organic-inorganic halide solar cells by doping a donor polymer
	Zhang, CC; Li, M; Wang, ZK; Jiang, YR; Liu, HR; Yang, YG; Gao, XY; Ma, H
	2017
发表期刊	JOURNAL OF MATERIALS CHEMISTRY A
ISSN	2050-7488
卷号	5 期号:6 页码:2572-2579
文章类型	期刊论文
摘要	Photovoltaic performance of planar perovskite hybrid solar cells (pero-HSCs) has been improved by mixing CH(3)NH(3)PbIxCl(3-x) and an electron donor polymer [ N-9''-hepta-hecanyl- 2,7-carbazole-alt- 5,5-(4',7'-di-2-thienyl- 2',1',3'-benzothiadiaz-ole)] (PCDTBT). PCDTBT contains lone pairs of electrons due to the presence of S and N atoms, which could passivate the trap states of the perovskite layer and thus reduce the number of film defects. A Stonehenge-like structure could be formed by the interaction of CH(3)NH(3)PbIxCl(3-x) and PCDTBT, developing more ordered orientation crystallization and a high quality film morphology. The doped solar cells are characterized by their excellent photovoltaic properties and enhanced stability. When the doping concentration is 0.3 mg mL(-1), the fabricated solar cell device exhibits an outstanding power conversion efficiency (PCE) of 15.76%, which represents a significant improvement with respect to the magnitude of 16% obtained for the reference device.
DOI	10.1039/c6ta08970d
收录类别	SCI
语种	英语
WOS记录号	WOS:000395075600020
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/27407
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Zhang, CC,Li, M,Wang, ZK,et al. Passivated perovskite crystallization and stability in organic-inorganic halide solar cells by doping a donor polymer[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(6):2572-2579.
APA	Zhang, CC.,Li, M.,Wang, ZK.,Jiang, YR.,Liu, HR.,...&Ma, H.(2017).Passivated perovskite crystallization and stability in organic-inorganic halide solar cells by doping a donor polymer.JOURNAL OF MATERIALS CHEMISTRY A,5(6),2572-2579.
MLA	Zhang, CC,et al."Passivated perovskite crystallization and stability in organic-inorganic halide solar cells by doping a donor polymer".JOURNAL OF MATERIALS CHEMISTRY A 5.6(2017):2572-2579.

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