CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets
Wang, T; Wang, WL; Lyu, Y; Xiong, K; Li, CY; Zhang, H; Zhan, ZP; Jiang, Z; Ding, YJ
2017
Source PublicationCHINESE JOURNAL OF CATALYSIS
ISSN0253-9837
Volume38Issue:4Pages:691-698
Subtype期刊论文
AbstractA new chiral monomer, (S)-5,5'-divinyl-BINAP, was successfully synthesized and embedded into two different porous organic polymers (Poly-1 and Poly-2). After loading a Rh species, the catalysts were applied for the heterogeneous asymmetric hydroformylation of styrene. Compared with the homogeneous BINAP analogue, the enantioselectivity of Rh/Poly-1 catalyst was drastically increased by approximately 70%. The improved enantioselectivity of the porous Rh/BINAP polymers was attributed to the presence of flexible chiral nanopockets resulting from the increased bulk of the R groups near the catalytic center. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
KeywordPorous Organic Polymer Heterogeneous Catalysis Asymmetric Hydroformylation Enhanced Enatioselectivity Chiral Nanopocket
DOI10.1016/S1872-2067(17)62790-6
Indexed BySCI
Language英语
WOS IDWOS:000400419900009
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/27415
Collection中科院上海应用物理研究所2011-2018年
Recommended Citation
GB/T 7714
Wang, T,Wang, WL,Lyu, Y,et al. Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(4):691-698.
APA Wang, T.,Wang, WL.,Lyu, Y.,Xiong, K.,Li, CY.,...&Ding, YJ.(2017).Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets.CHINESE JOURNAL OF CATALYSIS,38(4),691-698.
MLA Wang, T,et al."Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets".CHINESE JOURNAL OF CATALYSIS 38.4(2017):691-698.
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