中国科学院上海应用物理研究所机构知识库
Advanced  
CAS OpenIR  > 中科院上海应用物理研究所2011-2017年  > 期刊论文
题名:
Probing Chemical Bonding and Electronic Structures in ThO- by Anion Photoelectron Imaging and Theoretical Calculations
作者: Li, YL; Zou, JH; Xiong, XG; Su, J; Xie, H; Fei, ZJ; Tang, ZC; Liu, HT
刊名: JOURNAL OF PHYSICAL CHEMISTRY A
出版日期: 2017
卷号: 121, 期号:10, 页码:2108-2113
DOI: 10.1021/acs.jpca.6b11554
文章类型: 期刊论文
英文摘要: Because of renewed research on thorium-based molten salt reactors, there is growing demand and interest in enhancing the knowledge of thorium chemistry both experimentally and theoretically. Compared with uranium, thorium has few chemical studies reported up to the present. Here we report the vibrationally resolved photoelectron imaging of the thorium monoxide anion. The electron affinity of ThO is first reported to be 0.707 +/- 0.020 eV. Vibrational frequencies of the ThO molecule and its anion are determined from Franck Condon simulation. Spectroscopic evidence is obtained for the two-electron transition in ThO-, indicating the strong electron correlation among the (7s sigma)(2)(6d delta)(1) electrons in ThO- and the (7s sigma)(2) electrons in ThO. These findings are explained by using quantum-chemical calculations including spin orbit coupling, and the chemical bonding of gaseous ThO molecules is analyzed. The present work will enrich our understanding of bonding capacities with the 6d valence shell.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000396969400005
ISSN号: 1089-5639
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/27422
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
Probing Chemical Bonding and Electronic Structures in ThO- by Anion Photoelectron Imaging and Theoretical Calculations.pdf(1444KB)期刊论文作者接受稿开放获取View Download

Recommended Citation:
Li, YL,Zou, JH,Xiong, XG,et al. Probing Chemical Bonding and Electronic Structures in ThO- by Anion Photoelectron Imaging and Theoretical Calculations[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2017-01-01,121(10):2108-2113.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Li, YL]'s Articles
[Zou, JH]'s Articles
[Xiong, XG]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Li, YL]‘s Articles
[Zou, JH]‘s Articles
[Xiong, XG]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: Probing Chemical Bonding and Electronic Structures in ThO- by Anion Photoelectron Imaging and Theoretical Calculations.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace