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| Simulated solar driven catalytic degradation of psychiatric drug carbamazepine with binary BiVO4 heterostructures sensitized by graphene quantum dots | |
| Tang, L; Wang, JJ; Jia, CT; Lv, GX; Xu, G; Li, WT; Wang, L; Zhang, JY; Wu, MH | |
| 2017 | |
| 发表期刊 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| ISSN | 0926-3373 |
| 卷号 | 205页码:587-596 |
| 文章类型 | 期刊论文 |
| 摘要 | Herein, solar-driven GQDs loaded BiVO4 heterostructure catalysts were fabricated and employed to degradate carbamazepine (CBZ) under simulated solar light. The as-prepared ternary catalysts (GQD/m-BiVO4/t-BiVO4) were thoroughly characterized by TEM, HRTEM, XRD, XPS, UV-vis, Raman and PL. The characterization results demonstrated that GQDs are well-dispersed on binary BiVO4 support, and the optical properties of the composites are improved with GQDs loaded. The photocatalytic activities of the novel composite catalysts were significantly increased by incorporation of GQDs on original BiVO4 semiconductor. In particular, the 1.0 wt% GQD loaded catalysts exhibited the highest photocatalytic activity for CBZ, and the mineralization degree of CBZ with the catalysts could achieve more than 95%. In addition, the transformation products (TPs) of CBZ during the catalysis processes were tentatively identified, and hydroxyl radicals were regarded as the predominant active species. From the results of density functional theory (DFT) calculations and evolution of TPs, hydroxylation and cleavage of amide group on the heterocycle may be the main initial photocatalytic degradation channels for CBZ under the catalysis of GQD/BiVO4. (C) 2016 Published by Elsevier B.V. |
| 关键词 | Gqd/m-biva(4)/t-bivo4 Simulated Solar-light Photocatalysis Carbamazepine Mechanisms |
| DOI | 10.1016/j.apcatb.2016.10.067 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000393931000061 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.sinap.ac.cn/handle/331007/27443 |
| 专题 | 中科院上海应用物理研究所2011-2018年 |
| 推荐引用方式 GB/T 7714 | Tang, L,Wang, JJ,Jia, CT,et al. Simulated solar driven catalytic degradation of psychiatric drug carbamazepine with binary BiVO4 heterostructures sensitized by graphene quantum dots[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2017,205:587-596. |
| APA | Tang, L.,Wang, JJ.,Jia, CT.,Lv, GX.,Xu, G.,...&Wu, MH.(2017).Simulated solar driven catalytic degradation of psychiatric drug carbamazepine with binary BiVO4 heterostructures sensitized by graphene quantum dots.APPLIED CATALYSIS B-ENVIRONMENTAL,205,587-596. |
| MLA | Tang, L,et al."Simulated solar driven catalytic degradation of psychiatric drug carbamazepine with binary BiVO4 heterostructures sensitized by graphene quantum dots".APPLIED CATALYSIS B-ENVIRONMENTAL 205(2017):587-596. |
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| Simulated solar driv（3532KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 | |
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