Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Small Molecule Polymer Composite Hole-Transporting Layer for Highly Efficient and Stable Perovskite Solar Cells | |
| Wang, JM; Wang, ZK; Li, M; Hu, KH; Yang, YG; Hu, Y; Gao, XY; Liao, LS | |
| 2017 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
 |
| ISSN | 1944-8244 |
| Volume | 9Issue:15Pages:13240-13246 |
| Subtype | 期刊论文 |
| Abstract | Effective and stable hole-transporting materials (HTMs) are necessary for obtaining excellent planar perovskite solar cells (PSCs). Herein, we reported a solution-processed composite HTM consisting of a polymer poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) and a small-molecule copper phthalocyanine-3,4 ',4 '',4 '''-tetrasulfonated acid tetrasodium salt (TS-CuPc) with optimized doping ratios. The composite HTM is crucial for not only enhancing the hole transport and extraction but also improving the perovskite crystallization. In addition, the composite HTM can weaken the indium tin oxide erosion by reducing the acidity and increasing the dispersibility of the PEDOT:PSS aqueous dispersion via incorporating suitable TS CuPc. Consequently, a highly efficient device was fabricated with a power conversion efficiency (PCE) of 17.29%. Its short-circuit current (J(SC)) is 22.23 mA/cm(2), and its open-circuit voltage (V-OC) is 1.01 Meanwhile, it exhibited a higher fill factor (FF) of 77% and improved cell stability. The developed composite HTM provides a good potential anode interfacial layer for fabricating outstanding PSCs. |
| Keyword | Perovskite Solar Cells (Pscs) Small Molecule-polymer Hole-transporting Layer High Efficiency High Stability |
| DOI | 10.1021/acsami.7b02223 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000399965700036 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27445 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Wang, JM,Wang, ZK,Li, M,et al. Small Molecule Polymer Composite Hole-Transporting Layer for Highly Efficient and Stable Perovskite Solar Cells[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(15):13240-13246. |
| APA | Wang, JM.,Wang, ZK.,Li, M.,Hu, KH.,Yang, YG.,...&Liao, LS.(2017).Small Molecule Polymer Composite Hole-Transporting Layer for Highly Efficient and Stable Perovskite Solar Cells.ACS APPLIED MATERIALS & INTERFACES,9(15),13240-13246. |
| MLA | Wang, JM,et al."Small Molecule Polymer Composite Hole-Transporting Layer for Highly Efficient and Stable Perovskite Solar Cells".ACS APPLIED MATERIALS & INTERFACES 9.15(2017):13240-13246. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Small Molecule Polym（3460KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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