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CAS OpenIR  > 中科院上海应用物理研究所2011-2017年  > 期刊论文
题名:
The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques
作者: Song, YX; Hu, JG; Tang, J; Gu, WM; Fu, YN; Ji, XB
刊名: JOURNAL OF THE ELECTROCHEMICAL SOCIETY
出版日期: 2017
卷号: 164, 期号:4, 页码:D230-D236
DOI: 10.1149/2.1371704jes
文章类型: 期刊论文
英文摘要: Resorted to the advanced synchrotron radiation techniques, the interfacial evolution behaviors of zinc electrodeposits from ammonium chloride media have been disclosed using ex situ X-ray absorption spectroscopy (XAS) and real-time dynamic X-ray imaging (DXI). The XAS spectra indicate that the predominant zinc(II) species in ammonium chloride media present a tetrahedral configuration independent on aqueous pH. However, the DXI results suggest that the diverse morphologies of zinc deposits are highly dependent on aqueous pH due to the change of inner coordination sphere of zinc species. Moreover, the anodic stripping of zinc deposits firstly results from the dissolution of compact deposits at the substrate side. These observations provide a deep interfacial insight on zinc electrodeposition in ammonium chloride media, thereby allowing the morphologies of metal electrodeposits to be better regulated through the change of solution chemistry. (C) 2017 The Electrochemical Society. All rights reserved.
收录类别: SCI
语种: 英语
WOS记录号: WOS:000400958600106
ISSN号: 0013-4651
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sinap.ac.cn/handle/331007/27471
Appears in Collections:中科院上海应用物理研究所2011-2017年_期刊论文

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Recommended Citation:
Song, YX,Hu, JG,Tang, J,et al. The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2017-01-01,164(4):D230-D236.
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文件名: The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques.pdf
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