CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques
Song, YX; Hu, JG; Tang, J; Gu, WM; Fu, YN; Ji, XB
2017
Source PublicationJOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN0013-4651
Volume164Issue:4Pages:D230-D236
Subtype期刊论文
AbstractResorted to the advanced synchrotron radiation techniques, the interfacial evolution behaviors of zinc electrodeposits from ammonium chloride media have been disclosed using ex situ X-ray absorption spectroscopy (XAS) and real-time dynamic X-ray imaging (DXI). The XAS spectra indicate that the predominant zinc(II) species in ammonium chloride media present a tetrahedral configuration independent on aqueous pH. However, the DXI results suggest that the diverse morphologies of zinc deposits are highly dependent on aqueous pH due to the change of inner coordination sphere of zinc species. Moreover, the anodic stripping of zinc deposits firstly results from the dissolution of compact deposits at the substrate side. These observations provide a deep interfacial insight on zinc electrodeposition in ammonium chloride media, thereby allowing the morphologies of metal electrodeposits to be better regulated through the change of solution chemistry. (C) 2017 The Electrochemical Society. All rights reserved.
DOI10.1149/2.1371704jes
Indexed BySCI
Language英语
WOS IDWOS:000400958600106
Citation statistics
Cited Times:5[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/27471
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Song, YX,Hu, JG,Tang, J,et al. The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2017,164(4):D230-D236.
APA Song, YX,Hu, JG,Tang, J,Gu, WM,Fu, YN,&Ji, XB.(2017).The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,164(4),D230-D236.
MLA Song, YX,et al."The Dynamic Interfacial Understanding of Zinc Electrodeposition in Ammoniacal Media through Synchrotron Radiation Techniques".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 164.4(2017):D230-D236.
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