Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| The extraction of uranium using graphene aerogel loading organic solution | |
| Chen, MM; Li, Z; Li, JH; Li, JG; Li, QN; Zhang, L | |
| 2017 | |
| Source Publication | TALANTA
 |
| ISSN | 0039-9140 |
| Volume | 166Pages:284-291 |
| Subtype | 期刊论文 |
| Abstract | A new approach for uranium extraction employing graphene aerogel (GA) as a skeleton loading organic solution (GA-LOS) is proposed and investigated. Firstly, the GA with super-hydrophobicity and high organic solution absorption capacity was fabricated by one-step reduction and self-assembly of graphene oxide with ethylenediamine. By adsorbing Tri-n-butyl phosphate (TBP)/n-dodecane solution to prepare GA-LOS, the extraction of U(VI) from nitric acid medium using GA-LOS was investigated and compared with conventional solvent extraction. It is found that the GA-LOS method can provide several advantages over conventional solvent extraction and adsorption due to the elimination of aqueous-organic mixing-separation procedures and easy solid-liquid separation. Furthermore, it also possesses higher extraction capacity (the saturated extraction capacity of GA loading TBP for U(VI) was 316.3 mg g(-1)) and lower consumption of organic diluents, leading to less organic waste. Moreover, the stability of GA-LOS in aqueous solution and cycling test were also studied, and it shows a remarkable regeneration capability, making it an ideal candidate for metal extraction from aqueous solution. |
| Keyword | Solvent Extraction Graphene Aerogel Superhydrophobic Uranium |
| DOI | 10.1016/j.talanta.2017.01.070 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000395839700039 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27476 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Chen, MM,Li, Z,Li, JH,et al. The extraction of uranium using graphene aerogel loading organic solution[J]. TALANTA,2017,166:284-291. |
| APA | Chen, MM,Li, Z,Li, JH,Li, JG,Li, QN,&Zhang, L.(2017).The extraction of uranium using graphene aerogel loading organic solution.TALANTA,166,284-291. |
| MLA | Chen, MM,et al."The extraction of uranium using graphene aerogel loading organic solution".TALANTA 166(2017):284-291. |
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| The extraction of ur（1094KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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