Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems

doi:10.1007/s40242-017-6137-7

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	Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems
	An, XH; Zhang, P; Cheng, JH; Chen, SL; Wang, JQ
	2017
发表期刊	CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN	1005-9040
卷号	33 期号:1 页码:122-128
文章类型	期刊论文
摘要	Phase equilibria and thermodynamic properties of the CsNO3-KNO3-NaNO3 system and its three subsystems were optimized thermodynamically and validated experimentally. The liquid and end solid solution phases of the KNO3-NaNO3 and CsNO3-KNO3 systems were modeled using the substitutional solution and compound energy formalism models, respectively. The CsNO3-KNO3-NaNO3 ternary system was described thermodynamically based on the self-consistent thermodynamic parameters of the three binary systems. A set of thermodynamic parameters was obtained to reproduce the available information on the thermodynamic properties and phase equilibria. Melting temperature, enthalpy, and specific heat capacity of a eutectic sample were determined using differential scanning calorimetry(DSC). The results show a good consistency with the calculated results, suggesting the reliability of the current thermodynamic database. This work is useful for the construction of multicomponent nitrates and to provide guidance for the development of new medium for thermal energy storage.
关键词	Thermal Energy Storage Nitrate Calphad Phase Diagram
DOI	10.1007/s40242-017-6137-7
收录类别	SCI
语种	英语
WOS记录号	WOS:000393536800020
引用统计	被引频次：4[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/27485
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	An, XH,Zhang, P,Cheng, JH,et al. Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(1):122-128.
APA	An, XH,Zhang, P,Cheng, JH,Chen, SL,&Wang, JQ.(2017).Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(1),122-128.
MLA	An, XH,et al."Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.1(2017):122-128.

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