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Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems
An, XH; Zhang, P; Cheng, JH; Chen, SL; Wang, JQ
2017
Source PublicationCHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
Volume33Issue:1Pages:122-128
Subtype期刊论文
AbstractPhase equilibria and thermodynamic properties of the CsNO3-KNO3-NaNO3 system and its three subsystems were optimized thermodynamically and validated experimentally. The liquid and end solid solution phases of the KNO3-NaNO3 and CsNO3-KNO3 systems were modeled using the substitutional solution and compound energy formalism models, respectively. The CsNO3-KNO3-NaNO3 ternary system was described thermodynamically based on the self-consistent thermodynamic parameters of the three binary systems. A set of thermodynamic parameters was obtained to reproduce the available information on the thermodynamic properties and phase equilibria. Melting temperature, enthalpy, and specific heat capacity of a eutectic sample were determined using differential scanning calorimetry(DSC). The results show a good consistency with the calculated results, suggesting the reliability of the current thermodynamic database. This work is useful for the construction of multicomponent nitrates and to provide guidance for the development of new medium for thermal energy storage.
KeywordThermal Energy Storage Nitrate Calphad Phase Diagram
DOI10.1007/s40242-017-6137-7
Indexed BySCI
Language英语
WOS IDWOS:000393536800020
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/27485
Collection中科院上海应用物理研究所2011-2018年
Recommended Citation
GB/T 7714
An, XH,Zhang, P,Cheng, JH,et al. Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(1):122-128.
APA An, XH,Zhang, P,Cheng, JH,Chen, SL,&Wang, JQ.(2017).Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(1),122-128.
MLA An, XH,et al."Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.1(2017):122-128.
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