Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems
An, XH; Zhang, P; Cheng, JH; Chen, SL; Wang, JQ
2017
发表期刊CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
卷号33期号:1页码:122-128
文章类型期刊论文
摘要Phase equilibria and thermodynamic properties of the CsNO3-KNO3-NaNO3 system and its three subsystems were optimized thermodynamically and validated experimentally. The liquid and end solid solution phases of the KNO3-NaNO3 and CsNO3-KNO3 systems were modeled using the substitutional solution and compound energy formalism models, respectively. The CsNO3-KNO3-NaNO3 ternary system was described thermodynamically based on the self-consistent thermodynamic parameters of the three binary systems. A set of thermodynamic parameters was obtained to reproduce the available information on the thermodynamic properties and phase equilibria. Melting temperature, enthalpy, and specific heat capacity of a eutectic sample were determined using differential scanning calorimetry(DSC). The results show a good consistency with the calculated results, suggesting the reliability of the current thermodynamic database. This work is useful for the construction of multicomponent nitrates and to provide guidance for the development of new medium for thermal energy storage.
关键词Thermal Energy Storage Nitrate Calphad Phase Diagram
DOI10.1007/s40242-017-6137-7
收录类别SCI
语种英语
WOS记录号WOS:000393536800020
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/27485
专题中科院上海应用物理研究所2011-2018年
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An, XH,Zhang, P,Cheng, JH,et al. Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(1):122-128.
APA An, XH,Zhang, P,Cheng, JH,Chen, SL,&Wang, JQ.(2017).Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(1),122-128.
MLA An, XH,et al."Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.1(2017):122-128.
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