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| Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems | |
| An, XH; Zhang, P; Cheng, JH; Chen, SL; Wang, JQ | |
| 2017 | |
| Source Publication | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| ISSN | 1005-9040 |
| Volume | 33Issue:1Pages:122-128 |
| Subtype | 期刊论文 |
| Abstract | Phase equilibria and thermodynamic properties of the CsNO3-KNO3-NaNO3 system and its three subsystems were optimized thermodynamically and validated experimentally. The liquid and end solid solution phases of the KNO3-NaNO3 and CsNO3-KNO3 systems were modeled using the substitutional solution and compound energy formalism models, respectively. The CsNO3-KNO3-NaNO3 ternary system was described thermodynamically based on the self-consistent thermodynamic parameters of the three binary systems. A set of thermodynamic parameters was obtained to reproduce the available information on the thermodynamic properties and phase equilibria. Melting temperature, enthalpy, and specific heat capacity of a eutectic sample were determined using differential scanning calorimetry(DSC). The results show a good consistency with the calculated results, suggesting the reliability of the current thermodynamic database. This work is useful for the construction of multicomponent nitrates and to provide guidance for the development of new medium for thermal energy storage. |
| Keyword | Thermal Energy Storage Nitrate Calphad Phase Diagram |
| DOI | 10.1007/s40242-017-6137-7 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000393536800020 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/27485 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | An, XH,Zhang, P,Cheng, JH,et al. Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(1):122-128. |
| APA | An, XH,Zhang, P,Cheng, JH,Chen, SL,&Wang, JQ.(2017).Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(1),122-128. |
| MLA | An, XH,et al."Thermodynamic Reevaluation and Experimental Validation of the CsNO3-KNO3-NaNO3 System and Its Subsystems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.1(2017):122-128. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Thermodynamic Reeval（880KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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