CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Arsenic sorption by red mud-modified biochar produced from rice straw
Wu, C; Huang, L; Xue, SG; Huang, YY; Hartley, W; Cui, MQ; Wong, MH
2017
Source PublicationENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
ISSN0944-1344
Volume24Issue:22Pages:18168-18178
Subtype期刊论文
AbstractRed mud-modified biochar (RM-BC) has been produced to be utilized as a novel adsorbent to remove As because it can effectively combine the beneficial features of red mud (rich metal oxide composition and porous structure) and biochar (large surface area and porous structure properties). SEM-EDS and XRD analyses demonstrated that red mud had loaded successfully on the surface of biochar. With the increasing of pH in solution, arsenate (As(V)) adsorption on RM-BC decreased while arsenite (As(III)) increased. Arsenate adsorption kinetics process on RM-BC fitted the pseudo-second-order model, while that of As(III) favored the Elovich model. All sorption isotherms produced superior fits with the Langmuir model. RM-BC exhibited improved As removal capabilities, with a maximum adsorption capacity (Q(max)) for As(V) of 5923 mu g g(-1), approximately ten times greater than that of the untreated BC (552.0 mu g g(-1)). Furthermore, it has been indicated that the adsorption of As(V) on RM-BC may be strongly associated with iron oxides (hematite and magnetite) and aluminum oxides (gibbsite) by X-ray absorption near-edge spectroscopy (XANES), which was possibly because of surface complexation and electrostatic interactions. RM-BC may be used as a valuable adsorbent for removing As in the environment due to the waste materials being relatively abundant.
KeywordZero-valent Iron Bauxite Residue Aqueous-solutions Alkaline Characteristics Aggregate Stability Natural Hematite Magnetic Biochar As(Iii) Removal Paddy Soil Adsorption
DOI10.1007/s11356-017-9466-7
WOS KeywordZERO-VALENT IRON ; BAUXITE RESIDUE ; AQUEOUS-SOLUTIONS ; ALKALINE CHARACTERISTICS ; AGGREGATE STABILITY ; NATURAL HEMATITE ; MAGNETIC BIOCHAR ; AS(III) REMOVAL ; PADDY SOIL ; ADSORPTION
Indexed BySCI
Language英语
WOS IDWOS:000407577800018
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28558
Collection中科院上海应用物理研究所2011-2018年
Recommended Citation
GB/T 7714
Wu, C,Huang, L,Xue, SG,et al. Arsenic sorption by red mud-modified biochar produced from rice straw[J]. ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,2017,24(22):18168-18178.
APA Wu, C.,Huang, L.,Xue, SG.,Huang, YY.,Hartley, W.,...&Wong, MH.(2017).Arsenic sorption by red mud-modified biochar produced from rice straw.ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,24(22),18168-18178.
MLA Wu, C,et al."Arsenic sorption by red mud-modified biochar produced from rice straw".ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH 24.22(2017):18168-18178.
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