Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation

doi:10.1126/sciadv.1603068

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation
	Mao, JJ; Chen, WX; He, DS; Wan, JW; Pei, JJ; Dong, JC; Wang, Y; An, PF; Jin, Z; Xing, W; Tang, HL; Zhuang, ZB; Liang, X; Huang, Y; Zhou, G; Wang, LY; Wang, DS; Li, YD
	2017
发表期刊	SCIENCE ADVANCES
ISSN	2375-2548
卷号	3 期号:8 页码:-
文章类型	期刊论文
摘要	Developing cost-effective, active, and durable electrocatalysts is one of the most important issues for the commercialization of fuel cells. Ultrathin Pt-Mo-Ni nanowires (NWs) with a diameter of similar to 2.5 nm and lengths of up to several micro-meters were synthesized via a H-2-assisted solution route (HASR). This catalyst was designed on the basis of the following three points: (i) ultrathin NWs with high numbers of surface atoms can increase the atomic efficiency of Pt and thus decrease the catalyst cost; (ii) the incorporation of Ni can isolate Pt atoms on the surface and produce surface defects, leading to high catalytic activity (the unique structure and superior activity were confirmed by spherical aberration-corrected electron microscopy measurements and ethanol oxidation tests, respectively); and (iii) the incorporation of Mo can stabilize both Ni and Pt atoms, leading to high catalytic stability, which was confirmed by experiments and density functional theory calculations. Furthermore, the developed HASR strategy can be extended to synthesize a series of Pt-Mo-M (M = Fe, Co, Mn, Ru, etc.) NWs. These multimetallic NWs would open up new opportunities for practical fuel cell applications.
关键词	Ray-absorption Spectroscopy Oxygen Reduction Reaction Augmented-wave Method Methanol Electrooxidation Electrocatalytic Activity Alloy Nanowires Platinum Nanocrystals Nanoparticles Durability
DOI	10.1126/sciadv.1603068
关键词[WOS]	RAY-ABSORPTION SPECTROSCOPY ; OXYGEN REDUCTION REACTION ; AUGMENTED-WAVE METHOD ; METHANOL ELECTROOXIDATION ; ELECTROCATALYTIC ACTIVITY ; ALLOY NANOWIRES ; PLATINUM ; NANOCRYSTALS ; NANOPARTICLES ; DURABILITY
收录类别	SCI
语种	英语
WOS记录号	WOS:000411589900071
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/28602
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Mao, JJ,Chen, WX,He, DS,et al. Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation[J]. SCIENCE ADVANCES,2017,3(8):-.
APA	Mao, JJ.,Chen, WX.,He, DS.,Wan, JW.,Pei, JJ.,...&Li, YD.(2017).Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation.SCIENCE ADVANCES,3(8),-.
MLA	Mao, JJ,et al."Design of ultrathin Pt-Mo-Ni nanowire catalysts for ethanol electrooxidation".SCIENCE ADVANCES 3.8(2017):-.

条目包含的文件		下载所有文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
Design of ultrathin （2170KB）	期刊论文	作者接受稿	开放获取	CC BY-NC-SA	浏览下载