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| Disorder effects on EXAFS modeling for catalysts working at elevated temperatures | |
| Sun, XP; Sun, FF; Sun, ZH; Chen, J; Du, XL; Wang, JQ; Jiang, Z; Huang, YY | |
| 2017 | |
| Source Publication | RADIATION PHYSICS AND CHEMISTRY
 |
| ISSN | 0969-806X |
| Volume | 137Issue:-Pages:93-98 |
| Subtype | 期刊论文 |
| Abstract | In-situ X-ray absorption fine structure spectroscopy (XAFS) has been widely used to study the structure around active site of catalysts at elevated pressures and temperatures for decades. However, methods of XAFS data analysis can vary significantly, depending on the disorder degree of the material system investigated. In this work, in-situ XAFS was explored to investigate the structural evolutions of the industry CuO/ZnO/Al2O3 catalyst for methanol synthesis at elevated temperatures in nitrogen (N-2) atmosphere. Due to the large Debye-Waller factor, data analysis using the conventional Gaussian mode resulted in erroneously contracted Cu-Cu bond distances which made the conventional Gaussian mode invalid in this system. To account for the deviation from harmonic behavior, the cumulant expansion technique was used to correct the error in the bond contraction, and the frequency pattern could be fully reproduced by considering cumulants up to C-3. In order to elucidate the contributions of the structure and thermal components to the Debye-Waller factors, the Einstein method was also used to analyze the data that provides a straightforward proof regarding the effect of the temperature on the in-situ XAFS experiment. (C) 2016 Elsevier Ltd. All rights reserved. |
| Keyword | Methanol Synthesis Catalysts Absorption Fine-structure Extended X-ray Reduction Temperature Cu/zno Catalysts Spectroscopy Hydrogenolysis Surface Phase Site |
| DOI | 10.1016/j.radphyschem.2016.01.039 |
| Indexed By | SCI |
| WOS Keyword | METHANOL SYNTHESIS CATALYSTS ; ABSORPTION FINE-STRUCTURE ; EXTENDED X-RAY ; REDUCTION TEMPERATURE ; CU/ZNO CATALYSTS ; SPECTROSCOPY ; HYDROGENOLYSIS ; SURFACE ; PHASE ; SITE |
| Language | 英语 |
| WOS ID | WOS:000404201800019 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/28613 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Recommended Citation GB/T 7714 | Sun, XP,Sun, FF,Sun, ZH,et al. Disorder effects on EXAFS modeling for catalysts working at elevated temperatures[J]. RADIATION PHYSICS AND CHEMISTRY,2017,137(-):93-98. |
| APA | Sun, XP.,Sun, FF.,Sun, ZH.,Chen, J.,Du, XL.,...&Huang, YY.(2017).Disorder effects on EXAFS modeling for catalysts working at elevated temperatures.RADIATION PHYSICS AND CHEMISTRY,137(-),93-98. |
| MLA | Sun, XP,et al."Disorder effects on EXAFS modeling for catalysts working at elevated temperatures".RADIATION PHYSICS AND CHEMISTRY 137.-(2017):93-98. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Disorder effects on （829KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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