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| Fluorine gradient-doped LiNi0.5Mn1.5O4 spinel with improved high voltage stability for Li-ion batteries | |
| Luo, Y; Li, HY; Lu, TL; Zhang, YX; Mao, SS; Liu, Z; Wen, W; Xie, JY; Yan, LQ | |
| 2017 | |
| Source Publication | ELECTROCHIMICA ACTA
 |
| ISSN | 0013-4686 |
| Volume | 238Issue:-Pages:237-245 |
| Subtype | 期刊论文 |
| Abstract | The fluorine gradient-doped LiNi0.5Mn1.5O4 spinels are synthesized by a facile one-step method and the effect of heat treatment on their structure, morphology, and electrochemical performance are investigated. The results show that introduction of fluorine leads to a larger lattice parameter and particle size, and the formation of F-enriched surface. Whereas at 400 degrees C, the fluorine gradient-doped LiNi0.5Mn1.5O4 sample exhibits an improved long-term cycling stability and high rate performance, due to` the suppression of the reaction between electrolyte and cathode, resulting in a decrease in the total resistance and the formation of a thin, uniform and smooth film on the surface. As a result of in situ XRD with charged pristine and the fluorine gradient-doped samples, the similar thermal-decomposition pathways from the charged spinel to the final NiMn2O4-type spinel structure with a small amount of NiMnO3 and alpha-Mn2O3 are observed. In addition, the disappearance temperature of the charged spinel structures is at about 280 degrees C for the fluorine gradient-doped sample, exhibiting an improved thermal stability of high voltage cathode material. These results show that fluorine gradient-doped LiNi0.5Mn1.5O4 sample is a promising positive electrode material for high performance lithium ion batteries. (C) 2017 Elsevier Ltd. All rights reserved. |
| Keyword | Electrochemical Performance Cathode Material Thermal-stability Surface Modification Limn1.5ni0.5-xmxo4 m Rate Capability Lithium Cation Electrodes Fe |
| DOI | 10.1016/j.electacta.2017.04.043 |
| WOS Keyword | ELECTROCHEMICAL PERFORMANCE ; CATHODE MATERIAL ; THERMAL-STABILITY ; SURFACE MODIFICATION ; LIMN1.5NI0.5-XMXO4 M ; RATE CAPABILITY ; LITHIUM ; CATION ; ELECTRODES ; FE |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000401113500027 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/28661 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Luo, Y,Li, HY,Lu, TL,et al. Fluorine gradient-doped LiNi0.5Mn1.5O4 spinel with improved high voltage stability for Li-ion batteries[J]. ELECTROCHIMICA ACTA,2017,238(-):237-245. |
| APA | Luo, Y.,Li, HY.,Lu, TL.,Zhang, YX.,Mao, SS.,...&Yan, LQ.(2017).Fluorine gradient-doped LiNi0.5Mn1.5O4 spinel with improved high voltage stability for Li-ion batteries.ELECTROCHIMICA ACTA,238(-),237-245. |
| MLA | Luo, Y,et al."Fluorine gradient-doped LiNi0.5Mn1.5O4 spinel with improved high voltage stability for Li-ion batteries".ELECTROCHIMICA ACTA 238.-(2017):237-245. |
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| Fluorine gradient-do（2202KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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