CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals
Li, H; Liu, X; Qi, SQ; Xu, LL; Shi, GS; Ding, YH; Yan, XY; Huang, Y; Geng, JX
2017
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume56Issue:45Pages:14090-14095
Subtype期刊论文
AbstractZeolites with molecular dimension pores are widely used in petrochemical and fine-chemical industries. While traditional solvothermal syntheses suffer from environmental, safety, and efficiency issues, the newly developed solvent-free synthesis is limited by zeolite crystal aggregation. Herein, we report well-dispersed and faceted silicalite ZSM-5 zeolite crystals obtained using a solvent-free synthesis facilitated by graphene oxide (GO). The selective interactions between the GO sheets and different facets, which are confirmed by molecular dynamics simulations, result in oriented growth of the ZSM-5 crystals along the c-axis. More importantly, the incorporation of GO sheets into the ZSM-5 crystals leads to the formation of mesopores. Consequently, the faceted ZSM-5 crystals exhibit hierarchical pore structures. This synthetic method is superior to conventional approaches because of the features of the ZSM-5 zeolite.
KeywordNonheme Iron Catalysts o Bond Homolysis High-spin Photodissociation Spectroscopy Electronic-structure Oxidation Reactions Complexes Photolysis Reactivity Nitride
DOI10.1002/ange.201707823
Indexed BySCI
WOS KeywordNONHEME IRON CATALYSTS ; O BOND HOMOLYSIS ; HIGH-SPIN ; PHOTODISSOCIATION SPECTROSCOPY ; ELECTRONIC-STRUCTURE ; OXIDATION REACTIONS ; COMPLEXES ; PHOTOLYSIS ; REACTIVITY ; NITRIDE
Language英语
WOS IDWOS:000413896400031
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28672
Collection中科院上海应用物理研究所2011-2019年
Recommended Citation
GB/T 7714
Li, H,Liu, X,Qi, SQ,et al. Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(45):14090-14095.
APA Li, H.,Liu, X.,Qi, SQ.,Xu, LL.,Shi, GS.,...&Geng, JX.(2017).Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(45),14090-14095.
MLA Li, H,et al."Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.45(2017):14090-14095.
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