Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for crossdehydrogenative- coupling reactions via single electron transfer

doi:10.1039/c7ra05726a

CAS OpenIR > 中科院上海应用物理研究所2011-2019年

	Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for crossdehydrogenative- coupling reactions via single electron transfer
	Lin, M; Dai, LX; Gu, J; Kang, LQ; Wang, YH; Si, R; Zhao, ZQ; Liu, WC; Fu, XF; Sun, LD; Zhang, YW; Yan, CH
	2017
Source Publication	RSC ADVANCES
ISSN	2046-2069
Volume	7 Issue:53 Pages:33078-33085
Subtype	期刊论文
Abstract	For converting a homogeneous synthetic chemistry reaction to a heterogeneous one, using nanocatalysts, it is essential to investigate the underlying principles and the associated dominant factors of methodologies between inorganic nanoparticles and organic substrates. Here it is reported that novel, hydrothermally synthesized ruthenium (Ru) nanoparticles performed differently in molecular oxygen activation via single electron transfer for cross-dehydrogenative-coupling reactions, following a volcano shaped relationship between their oxidation levels and catalytic activity. Characterizations and a systematic mechanism study indicated that Ru3+ sites contributed to more superoxo- or peroxo-like species being formed from molecular oxygen on Ru nanoparticles with a moderate oxidation level, and the Ru3+ were the highly active species which accelerate this cross-dehydrogenative-coupling reaction via single electron transfer.
Keyword	Shape-controlled Synthesis Carbon Bond Formation Platinum Nanoparticles Supercritical Water Terminal Alkynes Nanocrystals Catalysts Hydrogenation Xps Functionalization
DOI	10.1039/c7ra05726a
Indexed By	SCI
WOS Keyword	SHAPE-CONTROLLED SYNTHESIS ; CARBON BOND FORMATION ; PLATINUM NANOPARTICLES ; SUPERCRITICAL WATER ; TERMINAL ALKYNES ; NANOCRYSTALS ; CATALYSTS ; HYDROGENATION ; XPS ; FUNCTIONALIZATION
Language	英语
WOS ID	WOS:000404864100003
Citation statistics	Cited Times:1[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.sinap.ac.cn/handle/331007/28737
Collection	中科院上海应用物理研究所2011-2019年
Recommended Citation GB/T 7714	Lin, M,Dai, LX,Gu, J,et al. Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for crossdehydrogenative- coupling reactions via single electron transfer[J]. RSC ADVANCES,2017,7(53):33078-33085.
APA	Lin, M.,Dai, LX.,Gu, J.,Kang, LQ.,Wang, YH.,...&Yan, CH.(2017).Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for crossdehydrogenative- coupling reactions via single electron transfer.RSC ADVANCES,7(53),33078-33085.
MLA	Lin, M,et al."Moderate oxidation levels of Ru nanoparticles enhance molecular oxygen activation for crossdehydrogenative- coupling reactions via single electron transfer".RSC ADVANCES 7.53(2017):33078-33085.

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