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| Phase stability and incompressibility of tungsten boride (WB) researched by in-situ high pressure x-ray diffraction | |
| Fan, C; Liu, CJ; Peng, F; Tan, N; Tang, MJ; Zhang, Q; Wang, QM; Li, FJ; Wang, JH; Chen, Y; Liang, H; Guan, SX; Yang, K; Liu, J | |
| 2017 | |
| Source Publication | PHYSICA B-CONDENSED MATTER
 |
| ISSN | 0921-4526 |
| Volume | 521Issue:-Pages:6-12 |
| Subtype | 期刊论文 |
| Abstract | The binary tungsten boride, WB, has potential industrial applications as it not only has a high melting point but is generally harder and less compressible than the pure metals. Here, the physical and mechanical properties (phase stability, bulk modulus and compressibility) of WB were investigated by in situ high-pressure x-ray diffraction and theoretical calculations. Its crystal structure still remains stable even at the highest pressure of 63.7 GPa and room temperature for the diamond-anvil cell experiments. The pressure-volume (P-V) data were fitted using the Birch-Murnaghan EOS and the Vinet EOS to obtain the isothermal bulk modulus, K-0 = 452 (4) GPa and 451(3) GPa and its pressure derivative, K-0' = 4 (fixed) in the two sets of experiments with two different pressure transmitting mediums (PTMs), respectively. The excellent bulk modulus (K-0) is attributed to the high valence electron density of W atom, the layered and chain-like crystal structure of WB and the strong chemical bonds formed by Wand B atoms. Besides, anisotropic compression behavior of the unit-cell axes (a-and c-axes) of WB is manifested by experimental observations and theoretical calculations. This remarkably elastic property is closely related to the strongly directional bonding between W and B atoms. |
| Keyword | Superhard Materials Crystals Hardness Diborides Ceramics Strain |
| DOI | 10.1016/j.physb.2017.06.028 |
| WOS Keyword | SUPERHARD MATERIALS ; CRYSTALS ; HARDNESS ; DIBORIDES ; CERAMICS ; STRAIN |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000410633400002 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/28769 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Fan, C,Liu, CJ,Peng, F,et al. Phase stability and incompressibility of tungsten boride (WB) researched by in-situ high pressure x-ray diffraction[J]. PHYSICA B-CONDENSED MATTER,2017,521(-):6-12. |
| APA | Fan, C.,Liu, CJ.,Peng, F.,Tan, N.,Tang, MJ.,...&Liu, J.(2017).Phase stability and incompressibility of tungsten boride (WB) researched by in-situ high pressure x-ray diffraction.PHYSICA B-CONDENSED MATTER,521(-),6-12. |
| MLA | Fan, C,et al."Phase stability and incompressibility of tungsten boride (WB) researched by in-situ high pressure x-ray diffraction".PHYSICA B-CONDENSED MATTER 521.-(2017):6-12. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Phase stability and （1271KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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