Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate

doi:10.1007/s10967-017-5543-0

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate
	Li, RF; Cao, XJ; Zhao, HG; Liu, CX; Li, Z; Wang, JH; Zhang, L; Li, QG
	2017
发表期刊	JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN	0236-5731
卷号	314 期号:3 页码:1715-1725
文章类型	期刊论文
摘要	Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis products of DMHMP were analyzed qualitatively and quantitatively with gas and ion chromatograph, the possible radiolysis mechanism of DMHMP was also concluded. Moreover, the effect of structure on the radiolysis products and irradiation stability of neutral organophosphorus compound extractant was also discussed.
关键词	Dodecane-tributylphosphate Solutions Radiation Degradation Purex Process Separation Extraction Acid Chemistry n N-diethylhydroxylamine
DOI	10.1007/s10967-017-5543-0
关键词[WOS]	DODECANE-TRIBUTYLPHOSPHATE SOLUTIONS ; RADIATION DEGRADATION ; PUREX PROCESS ; SEPARATION ; EXTRACTION ; ACID ; N,N-DIETHYLHYDROXYLAMINE ; CHEMISTRY
收录类别	SCI
语种	英语
WOS记录号	WOS:000416545300027
引用统计
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/28790
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Li, RF,Cao, XJ,Zhao, HG,et al. Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017,314(3):1715-1725.
APA	Li, RF.,Cao, XJ.,Zhao, HG.,Liu, CX.,Li, Z.,...&Li, QG.(2017).Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,314(3),1715-1725.
MLA	Li, RF,et al."Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 314.3(2017):1715-1725.

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