Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate
Li, RF; Cao, XJ; Zhao, HG; Liu, CX; Li, Z; Wang, JH; Zhang, L; Li, QG
2017
发表期刊JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN0236-5731
卷号314期号:3页码:1715-1725
文章类型期刊论文
摘要Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis products of DMHMP were analyzed qualitatively and quantitatively with gas and ion chromatograph, the possible radiolysis mechanism of DMHMP was also concluded. Moreover, the effect of structure on the radiolysis products and irradiation stability of neutral organophosphorus compound extractant was also discussed.
关键词Dodecane-tributylphosphate Solutions Radiation Degradation Purex Process Separation Extraction Acid Chemistry n N-diethylhydroxylamine
DOI10.1007/s10967-017-5543-0
关键词[WOS]DODECANE-TRIBUTYLPHOSPHATE SOLUTIONS ; RADIATION DEGRADATION ; PUREX PROCESS ; SEPARATION ; EXTRACTION ; ACID ; N,N-DIETHYLHYDROXYLAMINE ; CHEMISTRY
收录类别SCI
语种英语
WOS记录号WOS:000416545300027
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/28790
专题中科院上海应用物理研究所2011-2018年
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Li, RF,Cao, XJ,Zhao, HG,et al. Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017,314(3):1715-1725.
APA Li, RF.,Cao, XJ.,Zhao, HG.,Liu, CX.,Li, Z.,...&Li, QG.(2017).Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,314(3),1715-1725.
MLA Li, RF,et al."Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 314.3(2017):1715-1725.
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