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Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate | |
Li, RF; Cao, XJ; Zhao, HG; Liu, CX; Li, Z; Wang, JH; Zhang, L; Li, QG | |
2017 | |
Source Publication | JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
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ISSN | 0236-5731 |
Volume | 314Issue:3Pages:1715-1725 |
Subtype | 期刊论文 |
Abstract | Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis products of DMHMP were analyzed qualitatively and quantitatively with gas and ion chromatograph, the possible radiolysis mechanism of DMHMP was also concluded. Moreover, the effect of structure on the radiolysis products and irradiation stability of neutral organophosphorus compound extractant was also discussed. |
Keyword | Dodecane-tributylphosphate Solutions Radiation Degradation Purex Process Separation Extraction Acid Chemistry n N-diethylhydroxylamine |
DOI | 10.1007/s10967-017-5543-0 |
Indexed By | SCI |
WOS Keyword | DODECANE-TRIBUTYLPHOSPHATE SOLUTIONS ; RADIATION DEGRADATION ; PUREX PROCESS ; SEPARATION ; EXTRACTION ; ACID ; N,N-DIETHYLHYDROXYLAMINE ; CHEMISTRY |
Language | 英语 |
WOS ID | WOS:000416545300027 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/28790 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Recommended Citation GB/T 7714 | Li, RF,Cao, XJ,Zhao, HG,et al. Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate[J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,2017,314(3):1715-1725. |
APA | Li, RF.,Cao, XJ.,Zhao, HG.,Liu, CX.,Li, Z.,...&Li, QG.(2017).Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate.JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY,314(3),1715-1725. |
MLA | Li, RF,et al."Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate".JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY 314.3(2017):1715-1725. |
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Radiolysis products (2224KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download |
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