Stretchable Ionic-Liquid-Based Gel Polymer Electrolytes for Lithium Ion Batteries
Guan, JP; Li, YJ; Li, JY
2017
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号56期号:44页码:12456-12463
文章类型期刊论文
摘要Stretchable cross-linked gel polymer electrolytes (C-GPEs) have been fabricated through electron-beam irradiation (EBI) of poly(vinylidene fluoride-co-hexafluoropropylene) [P(VDF-co-HFP)]/triallyl isocyanurate (TAIC) blend films followed by adsorption of the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIm][TFSI]). It was found that polymer films containing 5 wt % cross-linker exhibit an excellent IL uptake value of 3.0 when irradiated at 75 kGy. The prepared C-GPEs have a high ion conductivity of 1.4 mS/cm at room temperature compared with a value of 0.7 mS/cm for P(VDF-co-HFP)/IL (1/3, m/m) blend gel. Morphological measurements indicate interconnected nanoporous structures in the films that can provide effective channels for ion immigration. Moreover, the C-GPEs show a high tensile strength of 10.6 MPa and an excellent elasticity, with almost full strain recovery after 100% stretch. In a LiFePO4/C-GPE/Li half-cell, the C-GPEs exhibit high electrochemical stability. Therefore, we consider that the prepared C-GPEs might have a potential application in flexible or/and stretchable energy storage devices.
关键词Membrane Fuel-cells Cross-linking Performance Supercapacitors Nanocomposite Conduction Matrix Salts Pvdf
DOI10.1021/acs.iecr.7b03387
关键词[WOS]MEMBRANE FUEL-CELLS ; CROSS-LINKING ; PERFORMANCE ; SUPERCAPACITORS ; NANOCOMPOSITE ; CONDUCTION ; MATRIX ; SALTS ; PVDF
收录类别SCI
语种英语
WOS记录号WOS:000415028300004
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/28830
专题中科院上海应用物理研究所2011-2018年
推荐引用方式
GB/T 7714
Guan, JP,Li, YJ,Li, JY. Stretchable Ionic-Liquid-Based Gel Polymer Electrolytes for Lithium Ion Batteries[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2017,56(44):12456-12463.
APA Guan, JP,Li, YJ,&Li, JY.(2017).Stretchable Ionic-Liquid-Based Gel Polymer Electrolytes for Lithium Ion Batteries.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,56(44),12456-12463.
MLA Guan, JP,et al."Stretchable Ionic-Liquid-Based Gel Polymer Electrolytes for Lithium Ion Batteries".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 56.44(2017):12456-12463.
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