Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media

doi:10.1002/anie.201706602

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media
	Shen, HJ; Gracia-Espino, E; Ma, JY; Zang, KT; Luo, J; Wang, L; Gao, SS; Mamat, X; Hu, GZ; Wagberg, T; Guo, SJ
	2017
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
卷号	56 期号:44 页码:13800-13804
文章类型	期刊论文
摘要	Various advanced catalysts based on sulfur-doped Fe/N/C materials have recently been designed for the oxygen reduction reaction (ORR); however, the enhanced activity is still controversial and usually attributed to differences in the surface area, improved conductivity, or uncertain synergistic effects. Herein, a sulfur-doped Fe/N/C catalyst (denoted as Fe/SNC) was obtained by a template-sacrificing method. The incorporated sulfur gives a thiophene-like structure (C-S-C), reduces the electron localization around the Fe centers, improves the interaction with oxygenated species, and therefore facilitates the complete 4e(-) ORR in acidic solution. Owing to these synergistic effects, the Fe/SNC catalyst exhibits much better ORR activity than the sulfur-free variant (Fe/NC) in 0.5m H2SO4.
关键词	Nitrogen-doped Graphene Membrane Fuel-cells Mesoporous Carbon Free Catalysts Electrocatalysts Identification Cathode Nanoparticles Performance Insights
DOI	10.1002/anie.201706602
关键词[WOS]	NITROGEN-DOPED GRAPHENE ; MEMBRANE FUEL-CELLS ; MESOPOROUS CARBON ; FREE CATALYSTS ; ELECTROCATALYSTS ; IDENTIFICATION ; CATHODE ; NANOPARTICLES ; PERFORMANCE ; INSIGHTS
收录类别	SCI
语种	英语
WOS记录号	WOS:000413314800047
引用统计	被引频次：25[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.sinap.ac.cn/handle/331007/28845
专题	中科院上海应用物理研究所2011-2018年
推荐引用方式 GB/T 7714	Shen, HJ,Gracia-Espino, E,Ma, JY,et al. Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(44):13800-13804.
APA	Shen, HJ.,Gracia-Espino, E.,Ma, JY.,Zang, KT.,Luo, J.,...&Guo, SJ.(2017).Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(44),13800-13804.
MLA	Shen, HJ,et al."Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.44(2017):13800-13804.

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