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| Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media | |
| Shen, HJ; Gracia-Espino, E; Ma, JY; Zang, KT; Luo, J; Wang, L; Gao, SS; Mamat, X; Hu, GZ; Wagberg, T; Guo, SJ | |
| 2017 | |
| Source Publication | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| ISSN | 1433-7851 |
| Volume | 56Issue:44Pages:13800-13804 |
| Subtype | 期刊论文 |
| Abstract | Various advanced catalysts based on sulfur-doped Fe/N/C materials have recently been designed for the oxygen reduction reaction (ORR); however, the enhanced activity is still controversial and usually attributed to differences in the surface area, improved conductivity, or uncertain synergistic effects. Herein, a sulfur-doped Fe/N/C catalyst (denoted as Fe/SNC) was obtained by a template-sacrificing method. The incorporated sulfur gives a thiophene-like structure (C-S-C), reduces the electron localization around the Fe centers, improves the interaction with oxygenated species, and therefore facilitates the complete 4e(-) ORR in acidic solution. Owing to these synergistic effects, the Fe/SNC catalyst exhibits much better ORR activity than the sulfur-free variant (Fe/NC) in 0.5m H2SO4. |
| Keyword | Nitrogen-doped Graphene Membrane Fuel-cells Mesoporous Carbon Free Catalysts Electrocatalysts Identification Cathode Nanoparticles Performance Insights |
| DOI | 10.1002/anie.201706602 |
| WOS Keyword | NITROGEN-DOPED GRAPHENE ; MEMBRANE FUEL-CELLS ; MESOPOROUS CARBON ; FREE CATALYSTS ; ELECTROCATALYSTS ; IDENTIFICATION ; CATHODE ; NANOPARTICLES ; PERFORMANCE ; INSIGHTS |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000413314800047 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/28845 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Shen, HJ,Gracia-Espino, E,Ma, JY,et al. Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(44):13800-13804. |
| APA | Shen, HJ.,Gracia-Espino, E.,Ma, JY.,Zang, KT.,Luo, J.,...&Guo, SJ.(2017).Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(44),13800-13804. |
| MLA | Shen, HJ,et al."Synergistic Effects between Atomically Dispersed Fe-N-C and C-S-C for the Oxygen Reduction Reaction in Acidic Media".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.44(2017):13800-13804. |
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| Synergistic Effects （3846KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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