Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems
Li, X; Wang, K; Xie, MY; Wu, Z; Xie, LD
2017
发表期刊CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
卷号33期号:3页码:454-459
文章类型期刊论文
摘要Phase diagrams for the CsF-UF4 and CsF-ThF4 systems were modeled in the present work through computational thermodynamics. The associate solution model with various complex species(CsMF5, Cs2MF6 and Cs3MF7; M=Th, U) was used to thermodynamically describe the binary molten salts. A total of ten intermediate phases were treated as stoichiometric compounds with their Gibbs energies modeled according to the Neumann-Kopp rule. All these model parameters were optimized by the least squares procedure until good coincidence was achieved between the calculated results and most of the experimental data. The derived thermodynamic parameters will be merged into the multicomponent CsF-LiF-BeF2-ThF4-UF4 database for analyzing physicochemical behavior of CsF in the fuel salt of the molten salt breeder reactor.
关键词Binary-system h System Equilibria Li
DOI10.1007/s40242-017-6282-z
关键词[WOS]BINARY-SYSTEM ; H SYSTEM ; EQUILIBRIA ; LI
收录类别SCI
语种英语
WOS记录号WOS:000404375600022
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/28875
专题中科院上海应用物理研究所2011-2018年
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Li, X,Wang, K,Xie, MY,et al. Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(3):454-459.
APA Li, X,Wang, K,Xie, MY,Wu, Z,&Xie, LD.(2017).Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(3),454-459.
MLA Li, X,et al."Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.3(2017):454-459.
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