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| Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems | |
| Li, X; Wang, K; Xie, MY; Wu, Z; Xie, LD | |
| 2017 | |
| Source Publication | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| ISSN | 1005-9040 |
| Volume | 33Issue:3Pages:454-459 |
| Subtype | 期刊论文 |
| Abstract | Phase diagrams for the CsF-UF4 and CsF-ThF4 systems were modeled in the present work through computational thermodynamics. The associate solution model with various complex species(CsMF5, Cs2MF6 and Cs3MF7; M=Th, U) was used to thermodynamically describe the binary molten salts. A total of ten intermediate phases were treated as stoichiometric compounds with their Gibbs energies modeled according to the Neumann-Kopp rule. All these model parameters were optimized by the least squares procedure until good coincidence was achieved between the calculated results and most of the experimental data. The derived thermodynamic parameters will be merged into the multicomponent CsF-LiF-BeF2-ThF4-UF4 database for analyzing physicochemical behavior of CsF in the fuel salt of the molten salt breeder reactor. |
| Keyword | Binary-system h System Equilibria Li |
| DOI | 10.1007/s40242-017-6282-z |
| WOS Keyword | BINARY-SYSTEM ; H SYSTEM ; EQUILIBRIA ; LI |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000404375600022 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/28875 |
| Collection | 中科院上海应用物理研究所2011-2018年 |
| Recommended Citation GB/T 7714 | Li, X,Wang, K,Xie, MY,et al. Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(3):454-459. |
| APA | Li, X,Wang, K,Xie, MY,Wu, Z,&Xie, LD.(2017).Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(3),454-459. |
| MLA | Li, X,et al."Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.3(2017):454-459. |
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| Thermodynamic and Ph（807KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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