CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems
Li, X; Wang, K; Xie, MY; Wu, Z; Xie, LD
2017
Source PublicationCHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
Volume33Issue:3Pages:454-459
Subtype期刊论文
AbstractPhase diagrams for the CsF-UF4 and CsF-ThF4 systems were modeled in the present work through computational thermodynamics. The associate solution model with various complex species(CsMF5, Cs2MF6 and Cs3MF7; M=Th, U) was used to thermodynamically describe the binary molten salts. A total of ten intermediate phases were treated as stoichiometric compounds with their Gibbs energies modeled according to the Neumann-Kopp rule. All these model parameters were optimized by the least squares procedure until good coincidence was achieved between the calculated results and most of the experimental data. The derived thermodynamic parameters will be merged into the multicomponent CsF-LiF-BeF2-ThF4-UF4 database for analyzing physicochemical behavior of CsF in the fuel salt of the molten salt breeder reactor.
KeywordBinary-system h System Equilibria Li
DOI10.1007/s40242-017-6282-z
WOS KeywordBINARY-SYSTEM ; H SYSTEM ; EQUILIBRIA ; LI
Indexed BySCI
Language英语
WOS IDWOS:000404375600022
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28875
Collection中科院上海应用物理研究所2011-2018年
Recommended Citation
GB/T 7714
Li, X,Wang, K,Xie, MY,et al. Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(3):454-459.
APA Li, X,Wang, K,Xie, MY,Wu, Z,&Xie, LD.(2017).Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(3),454-459.
MLA Li, X,et al."Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.3(2017):454-459.
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