Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems
Xie, MY; Li, X; Ding, YP; Zhang, GX
2017
发表期刊CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
ISSN1005-9040
卷号33期号:5页码:794-798
文章类型期刊论文
摘要The phase equilibria for the MCI2-ThCI4(M: Mg, Ca, Sr, Ba) binary systems were critically evaluated and optimized based upon the CALPHAD approach.. The substitutional solution model(SSM) was used to describe the liquid phase. All the. intermediate compounds were treated as stoichiometric compounds of which Gibbs energies comply with the Neumann-Kopp rule. Thermodynamic model parameters optimization for respective phases was conducted by the least squares minimization procedure with required input data available from experimental measurements. Satisfactory agreements between all calculated results and experimental data were achieved which demonstrates that thermodynamic databases for the MCI2-ThCI4(M: Mg, Ca, Sr, Ba) binary systems were ultimately derived. in the present work allowing safe extrapolation into multi-component system for guiding relative industrial applications.
关键词Molten-salt Reactor Energy-storage Binary-system Thorium
DOI10.1007/s40242-017-7033-x
关键词[WOS]MOLTEN-SALT REACTOR ; ENERGY-STORAGE ; BINARY-SYSTEM ; THORIUM
收录类别SCI
语种英语
WOS记录号WOS:000412790500017
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/28876
专题中科院上海应用物理研究所2011-2018年
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Xie, MY,Li, X,Ding, YP,et al. Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(5):794-798.
APA Xie, MY,Li, X,Ding, YP,&Zhang, GX.(2017).Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(5),794-798.
MLA Xie, MY,et al."Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.5(2017):794-798.
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