CAS OpenIR  > 中科院上海应用物理研究所2011-2018年
Thermodynamic modeling of the GdF3-MF (M: Li, K, Rb, Cs) systems
Li, X; Wang, K; Xie, LD
2017
Source PublicationFLUID PHASE EQUILIBRIA
ISSN0378-3812
Volume449Issue:-Pages:18-27
Subtype期刊论文
AbstractThe phase equilibria and thermochemical data for the GdF3-MF (M: Li, K, Rb, Cs) binary systems were critically evaluated and optimized based upon the CALPHAD approach. Two kinds of models like associated and substitutional solution were used to describe the liquid phase where cations were apt to form short range order (SRO) and random mixing, respectively. All the intermediate compounds were treated as stoichiometric of which Gibbs energies comply with the Neumann-Kopp rule. Model parameters optimization for respective phases was conducted by the least squares minimization procedure with required input data available from experimental measurements and empirical predictions (ionic parameter function). Satisfactory agreements between all calculated results and experimental & predicted data were achieved which demonstrates that thermodynamic databases for the GdF3-MF (M: Li, K, Rb, Cs) binary systems were ultimately derived in the present work allowing safe extrapolation into multicomponent system for guiding relative industrial applications. (C) 2017 Published by Elsevier B.V.
KeywordMolten-salt Reactor Crystal-structure Alkali Fluorides Liquid-mixtures Phase-diagrams Binary-systems Thermochemistry Chemistry M=k Na
DOI10.1016/j.fluid.2017.06.007
WOS KeywordMOLTEN-SALT REACTOR ; CRYSTAL-STRUCTURE ; ALKALI FLUORIDES ; LIQUID-MIXTURES ; PHASE-DIAGRAMS ; BINARY-SYSTEMS ; THERMOCHEMISTRY ; CHEMISTRY ; M=K ; NA
Indexed BySCI
Language英语
WOS IDWOS:000407406100003
Citation statistics
Cited Times:2[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28877
Collection中科院上海应用物理研究所2011-2018年
Recommended Citation
GB/T 7714
Li, X,Wang, K,Xie, LD. Thermodynamic modeling of the GdF3-MF (M: Li, K, Rb, Cs) systems[J]. FLUID PHASE EQUILIBRIA,2017,449(-):18-27.
APA Li, X,Wang, K,&Xie, LD.(2017).Thermodynamic modeling of the GdF3-MF (M: Li, K, Rb, Cs) systems.FLUID PHASE EQUILIBRIA,449(-),18-27.
MLA Li, X,et al."Thermodynamic modeling of the GdF3-MF (M: Li, K, Rb, Cs) systems".FLUID PHASE EQUILIBRIA 449.-(2017):18-27.
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