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A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions
Qie, MY; Lin, J; Kong, F; Silver, MA; Yue, ZH; Wang, XM; Zhang, LJ; Bao, HL; Albrecht-Schmitt, TE; Wang, JQ
2018
Source PublicationINORGANIC CHEMISTRY
ISSN0020-1669
Volume57Issue:3Pages:1676-1683
Subtype期刊论文
AbstractThe exploration of phase formation in the f-element-bearing iodate selenate system has resulted in 14 novel rare-earth-containing iodate selenates, Ln(IO3)(SeO4) (Ln = La, Ce, Pr, Nd; LnISeO-1), Ln(IO3)(SeO4)(H2O) (Ln = Sm, Eu; LnISeO-2), and Ln(IO3)(SeO4)(H2O)(2)center dot H2O (Ln = Gd, Dy, Ho, Er, Tm, Yb, Lu, Y; LnISeO-3), as well as two new thorium iodate selenates, Th(OH)(IO3)(SeO4)(H2O) (ThISeO-1) and Th(IO3)2(SeO4) (ThISeO-2). LnISeO-3 and ThISeO-2 crystallize in the chiral space group P2(1)2(1)2(1), while LnISeO-1, LnISeO-2, and ThISeO-1 crystallize in the centrosymmetric space group P2(1)/c. The numbers of both coordinating and hydrating water molecules crystallized in LnISeO-1, LnISeO-2, and LnISeO-3 increase along these three series, in line with the increasingly negative values of hydration enthalpies of heavier trivalent lanthanide ions. Such a systematic change in compositions, especially the first coordination sphere of Ln, further induces structural rearrangements, including coordination number and dimensional reductions. More specifically, the structures of LnISeO-1, LnISeO-2, and LnISeO-3 have undergone transitions from 2D Ln-oxo layers with 10-coordinate Ln centers to 1D Ln-oxo chains with 9-coordinate Ln centers and then to OD Ln-oxo monomers with 8 coordinate Ln centers, respectively. The formation and characterization of this large family of Ln/Th iodate selenates suggest that such a mixed-anion system not only exhibits richer structural chemistry but also can be capable of generating intriguing properties, such as the second-harmonic generation (SHG) effect.
KeywordElectronic-energy Levels Lanthanide Aquo Ions Tellurite-sulfate Compounds Structural Evolution Magnetic-properties Uranium Phosphites Uranyl Iodate Frameworks Selenites Lattice
DOI10.1021/acs.inorgchem.7b03116
Indexed BySCI
Language英语
WOS IDWOS:000424730800083
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28907
Collection中科院上海应用物理研究所2011-2019年
Affiliation1.Qie, MY
2.Lin, J
3.Kong, F
4.Silver, MA
5.Yue, ZH
6.Wang, XM
7.Zhang, LJ
8.Bao, HL
9.Albrecht-Schmitt, TE
10.Wang, JQ
Recommended Citation
GB/T 7714
Qie, MY,Lin, J,Kong, F,et al. A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions[J]. INORGANIC CHEMISTRY,2018,57(3):1676-1683.
APA Qie, MY.,Lin, J.,Kong, F.,Silver, MA.,Yue, ZH.,...&Wang, JQ.(2018).A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions.INORGANIC CHEMISTRY,57(3),1676-1683.
MLA Qie, MY,et al."A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions".INORGANIC CHEMISTRY 57.3(2018):1676-1683.
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