Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages
Cao, LP; Wang, PP; Miao, XR; Dong, YH; Wang, H; Duan, HH; Yu, Y; Li, XP; Stang, PJ
2018
发表期刊JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
卷号140期号:22页码:7005-7011
文章类型期刊论文
摘要Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supra molecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. As a result, this diamondoid SCF exhibits an adamantanoid-to-adamantanoid substructure with two sets of pores, including the interior cavity of the adamantanoid cage and the extended adamantanoid space between the individual cages in the framework. In addition, the shape-controllable and highly ordered self-assembly of nanometer-sized diamondoid SCF is observed as micrometer-sized regular octahedrons by evaporation under heating in DMSO. This study demonstrates the potential application of supramolecular coordination complexes in the precise construction of highly regulated porous framework materials.
关键词Metal-organic Frameworks Rational Design Networks Chemistry Hydrogen Crystalline Complexes Polyhedra Cuboctahedron Metallacycles
DOI10.1021/jacs.8b03856
收录类别SCI
语种英语
WOS记录号WOS:000434895200041
引用统计
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/28971
专题中科院上海应用物理研究所2011-2018年
作者单位1.Cao, LP
2.Wang, PP
3.Miao, XR
4.Dong, YH
5.Wang, H
6.Duan, HH
7.Yu, Y
8.Li, XP
9.Stang, PJ
推荐引用方式
GB/T 7714
Cao, LP,Wang, PP,Miao, XR,et al. Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(22):7005-7011.
APA Cao, LP.,Wang, PP.,Miao, XR.,Dong, YH.,Wang, H.,...&Stang, PJ.(2018).Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(22),7005-7011.
MLA Cao, LP,et al."Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.22(2018):7005-7011.
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