CAS OpenIR  > 中科院上海应用物理研究所2011-2019年
Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages
Cao, LP; Wang, PP; Miao, XR; Dong, YH; Wang, H; Duan, HH; Yu, Y; Li, XP; Stang, PJ
2018
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume140Issue:22Pages:7005-7011
Subtype期刊论文
AbstractRecently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supra molecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. As a result, this diamondoid SCF exhibits an adamantanoid-to-adamantanoid substructure with two sets of pores, including the interior cavity of the adamantanoid cage and the extended adamantanoid space between the individual cages in the framework. In addition, the shape-controllable and highly ordered self-assembly of nanometer-sized diamondoid SCF is observed as micrometer-sized regular octahedrons by evaporation under heating in DMSO. This study demonstrates the potential application of supramolecular coordination complexes in the precise construction of highly regulated porous framework materials.
KeywordMetal-organic Frameworks Rational Design Networks Chemistry Hydrogen Crystalline Complexes Polyhedra Cuboctahedron Metallacycles
DOI10.1021/jacs.8b03856
Indexed BySCI
Language英语
WOS IDWOS:000434895200041
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sinap.ac.cn/handle/331007/28971
Collection中科院上海应用物理研究所2011-2019年
Affiliation1.Cao, LP
2.Wang, PP
3.Miao, XR
4.Dong, YH
5.Wang, H
6.Duan, HH
7.Yu, Y
8.Li, XP
9.Stang, PJ
Recommended Citation
GB/T 7714
Cao, LP,Wang, PP,Miao, XR,et al. Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(22):7005-7011.
APA Cao, LP.,Wang, PP.,Miao, XR.,Dong, YH.,Wang, H.,...&Stang, PJ.(2018).Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(22),7005-7011.
MLA Cao, LP,et al."Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.22(2018):7005-7011.
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