Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
| Experimental investigation and thermodynamic modeling of the LiNO3-RbNO3-AgNO3 system and its subsystems | |
| Li, X; Xie, LD | |
| 2018 | |
| Source Publication | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| ISSN | 0925-8388 |
| Volume | 736Pages:124-135 |
| Subtype | 期刊论文 |
| Abstract | Computational thermodynamics approach based on experimental values is applied to evaluation and optimization of the LiNO3-RbNO3-AgNO3 system and its subsystems in this work. The substitutional solution model (SSM) was used to describe all liquid phase. All the intermediate compounds were treated as stoichiometric of which Gibbs energies comply with the Neumann-Kopp rule. A set of self-consistent database with thermodynamic model parameters obtained for the LiNO3-RbNO3-AgNO3 subsystems and this database were used to predict thermodynamic properties of the LiNO3-RbNO3-AgNO3 ternary system. The calculated results were verified experimentally using differential scanning calorimetry (DSC) and X-ray diffraction (XRD) techniques, and the agreement between the experimental values and predicted values is satisfactory. The phase diagram of the LiNO3-RbNO3-AgNO3 ternary system contain two eutectic types: one eutectic (Liquid <-> alpha-AgNO3 + LiRb(NO3)(2) + AgRb(NO3)(2)) at 385.3 +/- 1.5 K and another eutectic (Liquid <-> LiRb(NO3)(2) + AgRb(NO3)(2) + AgRb2(NO3)(3)) at 398.8 +/- 1.5 K. Through computational thermodynamics approach, a multi-component system was successfully predicted and this approach will be applied to design and develop multi-component molten salt mixtures as thermal energy storage (TES) materials. (C) 2017 Elsevier B.V. All rights reserved. |
| Keyword | Phase-diagram Energy-storage Binary-systems Nitrate Mixtures Ternary-system Fused Nitrates Enthalpies Rubidium Lithium |
| DOI | 10.1016/j.jallcom.2017.11.071 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000418519600018 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/29012 |
| Collection | 中科院上海应用物理研究所2011-2019年 |
| Affiliation | 1.Li, X 2.Xie, LD |
| Recommended Citation GB/T 7714 | Li, X,Xie, LD. Experimental investigation and thermodynamic modeling of the LiNO3-RbNO3-AgNO3 system and its subsystems[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2018,736:124-135. |
| APA | Li, X,&Xie, LD.(2018).Experimental investigation and thermodynamic modeling of the LiNO3-RbNO3-AgNO3 system and its subsystems.JOURNAL OF ALLOYS AND COMPOUNDS,736,124-135. |
| MLA | Li, X,et al."Experimental investigation and thermodynamic modeling of the LiNO3-RbNO3-AgNO3 system and its subsystems".JOURNAL OF ALLOYS AND COMPOUNDS 736(2018):124-135. |
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| Experimental investi（2318KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download | |
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