Ice Melting to Release Reactants in Solution Syntheses
Wei, HH; Huang, K; Zhang, L; Ge, BH; Wang, D; Lang, JL; Ma, JY; Wang, D; Zhang, S; Li, QY; Zhang, RY; Hussain, N; Lei, M; Liu, LM; Wu, H
2018
发表期刊ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
卷号57期号:13页码:3354-3359
文章类型期刊论文
摘要Aqueous solution syntheses are mostly based on mixing two solutions with different reactants. It is shown that freezing one solution and melting it in another solution provides a new interesting strategy to mix chemicals and to significantly change the reaction kinetics and thermodynamics. For example, a precursor solution containing a certain concentration of AgNO3 was frozen and dropped into a reductive NaBH4 solution at about 0 degrees C. The ultra-slow release of reactants was successfully achieved. An ice-melting process can be used to synthesize atomically dispersed metals, including cobalt, nickel, copper, rhodium, ruthenium, palladium, silver, osmium, iridium, platinum, and gold, which can be easily extended to other solution syntheses (such as precipitation, hydrolysis, and displacement reactions) and provide a generalized method to redesign the interphase reaction kinetics and ion diffusion in wet chemistry.
关键词Single-atom Co Oxidation Active-sites Nucleation Growth Nanoparticles Catalysts Mechanisms Microscopy Evolution
DOI10.1002/anie.201711128
收录类别SCI
语种英语
WOS记录号WOS:000427235600011
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/29035
专题中科院上海应用物理研究所2011-2018年
作者单位1.Wei, HH
2.Huang, K
3.Zhang, L
4.Ge, BH
5.Wang, D
6.Lang, JL
7.Ma, JY
8.Wang, D
9.Zhang, S
10.Li, QY
11.Zhang, RY
12.Hussain, N
13.Lei, M
14.Liu, LM
15.Wu, H
推荐引用方式
GB/T 7714
Wei, HH,Huang, K,Zhang, L,et al. Ice Melting to Release Reactants in Solution Syntheses[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(13):3354-3359.
APA Wei, HH.,Huang, K.,Zhang, L.,Ge, BH.,Wang, D.,...&Wu, H.(2018).Ice Melting to Release Reactants in Solution Syntheses.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(13),3354-3359.
MLA Wei, HH,et al."Ice Melting to Release Reactants in Solution Syntheses".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.13(2018):3354-3359.
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