Improving waterproof/breathable performance of electrospun poly(vinylidene fluoride) fibrous membranes by thermo-pressing
Li, X; Lin, JY; Bian, FG; Zeng, YC
2018
发表期刊JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
ISSN0887-6266
卷号56期号:1页码:36-45
文章类型期刊论文
摘要Facing the ever-increasing demand for waterproof/breathable materials, a rapid and efficient fabrication method of these functional materials with excellent performance as well as robust mechanical properties remains challenging. Herein, a simple and scalable strategy referred to as thermo-pressing is introduced to improve the waterproof/breathable performance and mechanical properties of electrospun PVDF fibrous membranes. The synergistic effect of temperature and pressure acted on the electrospun PVDF membranes on the fiber morphology and crystal structure was investigated, which can be able to effectively enhance waterproof performance and mechanical properties, endowing the as-prepared membranes with a modest breathability. The membranes thermo-pressed at 150 degrees C with a pressure of 8.27 MPa exhibit robust tensile strength of 40.65 MPa, which is superior to those of the previous reports (below 32.8 MPa). Notably, the optimized membranes enable to show a high hydrostatic pressure of 102 kPa, good WVTR of 10.87 kgm(-2)d(-1) and excellent abrasion resistance, which implies that the thermo-pressing is an efficient and facile way to steer the fiber morphology and crystal structure of electrospun membranes to improve their application performance. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 36-45
关键词Waterproof-breathable Application Nanofibrous Membranes Mechanical-properties Carbon Nanotubes Molecular-orientation Thin-films Fibers Fabrics Morphology Nanocomposites
DOI10.1002/polb.24534
收录类别SCI
语种英语
WOS记录号WOS:000416013700003
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sinap.ac.cn/handle/331007/29042
专题中科院上海应用物理研究所2011-2018年
作者单位1.Li, X
2.Lin, JY
3.Bian, FG
4.Zeng, YC
推荐引用方式
GB/T 7714
Li, X,Lin, JY,Bian, FG,et al. Improving waterproof/breathable performance of electrospun poly(vinylidene fluoride) fibrous membranes by thermo-pressing[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2018,56(1):36-45.
APA Li, X,Lin, JY,Bian, FG,&Zeng, YC.(2018).Improving waterproof/breathable performance of electrospun poly(vinylidene fluoride) fibrous membranes by thermo-pressing.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,56(1),36-45.
MLA Li, X,et al."Improving waterproof/breathable performance of electrospun poly(vinylidene fluoride) fibrous membranes by thermo-pressing".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 56.1(2018):36-45.
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