Knowledge Management System Of Shanghai Institute of Applied Physics, CAS
Phase transition of intermetallic TbPt at high temperature and high pressure | |
Qin, F; Wu, X; Yang, K; Qin, S | |
2018 | |
Source Publication | JOURNAL OF PHYSICS-CONDENSED MATTER
![]() |
ISSN | 0953-8984 |
Volume | 30Issue:14Pages:- |
Subtype | 期刊论文 |
Abstract | Here we present synchrotron-based x-ray diffraction experiments combined with diamond anvil cell and laser heating techniques on the intermetallic rare earth compound TbPt (Pnma and Z = 4) up to 32.5 GPa and similar to 1800 K. The lattice parameters of TbPt exhibit continuous compression behavior up to 18.2 GPa without any evidence of phase transformation. Pressure-volume data were fitted to a third-order Birch-Murnaghan equation of state with V-0 = 175.5(2) angstrom(3), K-T0 = 110(5) GPa and K-T0 = 3.8(7). TbPt exhibits anisotropic compression with ss(a) > ss(b) > ss(c) and the ratio of axial compressibility is 2.50:1.26:1.00. A new monoclinic phase of TbPt assigned to the Pc or P2/c space group was observed at 32.5 GPa after laser heating at similar to 1800 K. This new phase is stable at high pressure and presented a quenchable property on decompression to ambient conditions. The pressure-volume relationship is well described by the second-order Birch-Murnaghan equation of state, which yields V-0 = 672(4) angstrom(3), K-T0 = 123(6) GPa, which is about similar to 14% more compressible than the orthorhombic TbPt. Our results provide more information on the structure and elastic property view, and thus a better understanding of the physical properties related to magnetic structure in some intermetallic rare earth alloys. |
Keyword | Powder Diffraction Magnetic-properties X-ray Lif |
DOI | 10.1088/1361-648X/aaaf9b |
Indexed By | SCI |
Language | 英语 |
WOS ID | WOS:000427389700001 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.sinap.ac.cn/handle/331007/29101 |
Collection | 中科院上海应用物理研究所2011-2020年 |
Affiliation | 1.Qin, F 2.Wu, X 3.Yang, K 4.Qin, S |
Recommended Citation GB/T 7714 | Qin, F,Wu, X,Yang, K,et al. Phase transition of intermetallic TbPt at high temperature and high pressure[J]. JOURNAL OF PHYSICS-CONDENSED MATTER,2018,30(14):-. |
APA | Qin, F,Wu, X,Yang, K,&Qin, S.(2018).Phase transition of intermetallic TbPt at high temperature and high pressure.JOURNAL OF PHYSICS-CONDENSED MATTER,30(14),-. |
MLA | Qin, F,et al."Phase transition of intermetallic TbPt at high temperature and high pressure".JOURNAL OF PHYSICS-CONDENSED MATTER 30.14(2018):-. |
Files in This Item: | Download All | |||||
File Name/Size | DocType | Version | Access | License | ||
Phase transition of (918KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Download |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment