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| Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP) | |
| Li, RF; Cao, XJ; Zhao, HG; Liu, CX; Li, Z; Wang, JH; Zhang, L; Li, QG | |
| 2018 | |
| Source Publication | RADIOCHIMICA ACTA
 |
| ISSN | 0033-8230 |
| Volume | 106Issue:3Pages:239-247 |
| Subtype | 期刊论文 |
| Abstract | As an alternate extractant for spent fuel reprocessing, the radiolysis properties of TiAP should be systematically studied to evaluate the feasibility of using it in engineering scale. In this paper, the irradiation stability of TiAP was investigated by using the concept of radiolysis ratio and G value. It is found the extent of radiolysis would be increased with the increasing of absorbed doses, but decreased with the increasing of pre-equilibrium aqueous HNO3 concentration. Furthermore, the radiolysis products were analyzed qualitatively and quantitatively with gas, liquid and ion chromatograph, based on which the possible radiolysis mechanism of TiAP was also concluded. |
| Keyword | 3rd Phase-formation Dodecane-tributylphosphate Solutions Tributyl-phosphate Solvent-extraction Purex Process Separation Systems Actinides Diluent u(Vi) |
| DOI | 10.1515/ract-2017-2803 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000425945100007 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sinap.ac.cn/handle/331007/29119 |
| Collection | 中科院上海应用物理研究所2011-2020年 |
| Affiliation | 1.Li, RF 2.Cao, XJ 3.Zhao, HG 4.Liu, CX 5.Li, Z 6.Wang, JH 7.Zhang, L 8.Li, QG |
| Recommended Citation GB/T 7714 | Li, RF,Cao, XJ,Zhao, HG,et al. Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)[J]. RADIOCHIMICA ACTA,2018,106(3):239-247. |
| APA | Li, RF.,Cao, XJ.,Zhao, HG.,Liu, CX.,Li, Z.,...&Li, QG.(2018).Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP).RADIOCHIMICA ACTA,106(3),239-247. |
| MLA | Li, RF,et al."Radiolysis products and degradation mechanism studies on tri-isoamyl phosphate (TiAP)".RADIOCHIMICA ACTA 106.3(2018):239-247. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Radiolysis products （1588KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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