Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts

doi:10.1002/anie.201801103

CAS OpenIR > 中科院上海应用物理研究所2011-2018年

	Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts
	Xin, PY ; Li, J ; Xiong, Y ; Wu, X ; Dong, JC ; Chen, WX ; Wang, Y ; Gu, L ; Luo, J ; Rong, HP ; Chen, C ; Peng, Q ; Wang, DS ; Li, YD
	2018
Source Publication	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
Volume	57 Issue:17 Pages:4642-4646
Subtype	期刊论文
Abstract	The active species in supported metal catalysts are elusive to identify, and large quantities of inert species can cause significant waste. Herein, using a stoichiometrically precise synthetic method, we prepare atomically dispersed palladium-cerium oxide (Pd-1/CeO2) and hexapalladium cluster-cerium oxide (Pd-6/CeO2), as confirmed by spherical-aberration-corrected transmission electron microscopy and X-ray absorption fine structure spectroscopy. For aerobic alcohol oxidation, Pd-1/CeO2 shows extremely high catalytic activity with a TOF of 6739 h(-1) and satisfactory selectivity (almost 100% for benzaldehyde), while Pd-6/CeO2 is inactive, indicating that the true active species are single Pd atoms. Theoretical simulations reveal that the bulkier Pd-6 clusters hinder the interactions between hydroxy groups and the CeO2 surface, thus suppressing synergy of Pd-Ce perimeter.
Keyword	Single-atom Metal Nanoparticles Benzyl Alcohol Gold Pd Hydrogenation Dehydration Reactivity Mechanism Graphene
DOI	10.1002/anie.201801103
Indexed By	SCI
Language	英语
WOS ID	WOS:000430165700034
Citation statistics	Cited Times:8[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.sinap.ac.cn/handle/331007/29123
Collection	中科院上海应用物理研究所2011-2018年
Affiliation	1.Xin, PY 2.Li, J 3.Xiong, Y 4.Wu, X 5.Dong, JC 6.Chen, WX 7.Wang, Y 8.Gu, L 9.Luo, J 10.Rong, HP 11.Chen, C 12.Peng, Q 13.Wang, DS 14.Li, YD
Recommended Citation GB/T 7714	Xin, PY,Li, J,Xiong, Y,et al. Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(17):4642-4646.
APA	Xin, PY.,Li, J.,Xiong, Y.,Wu, X.,Dong, JC.,...&Li, YD.(2018).Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(17),4642-4646.
MLA	Xin, PY,et al."Revealing the Active Species for Aerobic Alcohol Oxidation by Using Uniform Supported Palladium Catalysts".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.17(2018):4642-4646.

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